Home / Publications / Catalytic synthesis of isoprenol from fatty acid ester over bimetallic Cu–Fe catalysts

Catalytic synthesis of isoprenol from fatty acid ester over bimetallic Cu–Fe catalysts

Anastasiya Alekseevna Shesterkina 1, 2
Anastasiya Alekseevna Shesterkina
, 
Anna Alekseevna Strekalova 1, 2
Anna Alekseevna Strekalova
, 
Elena Vladimirovna Shuvalova 1
Elena Vladimirovna Shuvalova
, 
Gennady Ivanovich Kapustin 1
Gennady Ivanovich Kapustin
, 
Olga P. Tkachenko 1
Olga P. Tkachenko
, 
Leonid Modestovich Kustov 1, 2, 3
Leonid Modestovich Kustov
10.1016/j.mencom.2022.09.035
Published 2022-09-05
Communication , Volume 32, Issue 5, 672-674
2
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Shesterkina A. A. et al. Catalytic synthesis of isoprenol from fatty acid ester over bimetallic Cu–Fe catalysts // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 672-674.
GOST all authors (up to 50) Copy
Shesterkina A. A., Strekalova A. A., Shuvalova E. V., Kapustin G. I., Tkachenko O. P., Kustov L. M. Catalytic synthesis of isoprenol from fatty acid ester over bimetallic Cu–Fe catalysts // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 672-674.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2022.09.035
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.035
TI - Catalytic synthesis of isoprenol from fatty acid ester over bimetallic Cu–Fe catalysts
T2 - Mendeleev Communications
AU - Shesterkina, Anastasiya Alekseevna
AU - Strekalova, Anna Alekseevna
AU - Shuvalova, Elena Vladimirovna
AU - Kapustin, Gennady Ivanovich
AU - Tkachenko, Olga P.
AU - Kustov, Leonid Modestovich
PY - 2022
DA - 2022/09/05
PB - Mendeleev Communications
SP - 672-674
IS - 5
VL - 32
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2022_Shesterkina,
author = {Anastasiya Alekseevna Shesterkina and Anna Alekseevna Strekalova and Elena Vladimirovna Shuvalova and Gennady Ivanovich Kapustin and Olga P. Tkachenko and Leonid Modestovich Kustov},
title = {Catalytic synthesis of isoprenol from fatty acid ester over bimetallic Cu–Fe catalysts},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.035},
number = {5},
pages = {672--674},
doi = {10.1016/j.mencom.2022.09.035}
}
MLA
Cite this
MLA Copy
Shesterkina, Anastasiya Alekseevna, et al. “Catalytic synthesis of isoprenol from fatty acid ester over bimetallic Cu–Fe catalysts.” Mendeleev Communications, vol. 32, no. 5, Sep. 2022, pp. 672-674. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.035.

Keywords

bimetallic catalyst
copper catalyst
hydrogenation
iron catalyst
isoprenol
isoprenyl acetate
nanoparticles

Abstract

Supported bimetallic Cu–Fe catalysts revealed high activity and selectivity in isoprenyl acetate hydrogenation to isoprenol under mild reaction conditions (2 MPa H2 and 170 °C). The nature of the carrier has a significant impact on the catalytic properties of Cu–Fe catalysts. The best catalytic properties were found for the 5% Cu–5% Fe/Al2O3 bimetallic catalyst, which provides a 98% isoprenyl acetate conversion in 4 h with the isoprenol selectivity of 82%.

References

1.
Biofuels, biodiesel and biohydrogen production using bioprocesses. A review
Srivastava R.K., Shetti N.P., Reddy K.R., Aminabhavi T.M.
Environmental Chemistry Letters, 2020
2.
Biofuels and renewable chemicals production by catalytic pyrolysis of cellulose: a review
Hassan N.S., Jalil A.A., Hitam C.N., Vo D.V., Nabgan W.
Environmental Chemistry Letters, 2020
5.
Biodiesel processing and production
Gerpen J.V.
Fuel Processing Technology, 2005
6.
Engineering Saccharomyces cerevisiae for isoprenol production
Kim J., Baidoo E.E., Amer B., Mukhopadhyay A., Adams P.D., Simmons B.A., Lee T.S.
Metabolic Engineering, 2021
7.
3-Methyl-3-buten-1-ol (isoprenol) confers longevity and stress tolerance in Caenorhabditis elegans
Pandey S., Phulara S.C., Jha A., Chauhan P.S., Gupta P., Shukla V.
International Journal of Food Sciences and Nutrition, 2019
8.
Recent advances in sustainable production and catalytic transformations of fatty acid methyl esters
Belousov A.S., Esipovich A.L., Kanakov E.A., Otopkova K.V.
Sustainable Energy and Fuels, 2021
9.
Selective hydrogenation of fatty acids and methyl esters of fatty acids to obtain fatty alcohols-a review
Sánchez M.A., Torres G.C., Mazzieri V.A., Pieck C.L.
Journal of Chemical Technology and Biotechnology, 2016
10.
Recent progress in hydrogenation of esters on heterogeneous bimetallic catalysts
Strekalova A.A., Shesterkina A.A., Kustov L.M.
Catalysis Science and Technology, 2021
11.
Thermal decomposition and reducibility of silica-supported precursors of Cu, Fe and Cu–Fe nanoparticles
Kirichenko O., Kapustin G., Nissenbaum V., Strelkova A., Shuvalova E., Shesterkina A., Kustov L.
Journal of Thermal Analysis and Calorimetry, 2018
12.
Kustov L.M., Tarasov A.L., Nissenbaum V.D., Kustov A.L.
Mendeleev Communications, 2021
13.
Evaluation of stability of silica-supported Fe–Pd and Fe–Pt nanoparticles in aerobic conditions using thermal analysis
Kirichenko O., Kapustin G., Nissenbaum V., Mishin I., Kustov L.
Journal of Thermal Analysis and Calorimetry, 2014
14.
Hydrodechlorination of chlorobenzene over supported metal catalysts
Lingaiah N., Seshu Babu N., Gopinath R., Siva Sankara Reddy P., Sai Prasad P.S.
Catalysis Surveys from Asia, 2006
16.
Thermal decomposition of precursors and iron oxide properties
dos Santos Monteiro D., da Guarda Souza M.O.
Journal of Thermal Analysis and Calorimetry, 2015
17.
Effect of ultra-low amount of gold in oxide-supported bimetallic Au–Fe and Au–Cu catalysts on liquid-phase aerobic glycerol oxidation in water
Redina E.A., Kapustin G.I., Tkachenko O.P., Greish A.A., Kustov L.M.
Catalysis Science and Technology, 2021
20.
FTIR study of CO interaction with Cu/TiO2
Venkov T., Hadjiivanov K.
Catalysis Communications, 2003
23.
An IR study of methanol steam reforming over ex-hydrotalcite Cu–Zn–Al catalysts
Larrubia Vargas M.A., Busca G., Costantino U., Marmottini F., Montanari T., Patrono P., Pinzari F., Ramis G.
Journal of Molecular Catalysis A Chemical, 2007