Home / Publications / Targeted preparation of highly efficient lithium extractants based on 14-membered crown ethers

Targeted preparation of highly efficient lithium extractants based on 14-membered crown ethers

Sergey Vladimirovich Nesterov 1, 2
Sergey Vladimirovich Nesterov
, 
Olga Anatol'evna Zakurdaeva 1, 2
Olga Anatol'evna Zakurdaeva
2 The Foundation for Support of Scientific and Project Activities of Students, Postgraduate Students and Young Scientists ‘National Intellectual Development’, Moscow, Russian Federation
10.1016/j.mencom.2022.09.034
Published 2022-09-05
Communication , Volume 32, Issue 5, 670-671
5
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Nesterov S. V., Zakurdaeva O. A. Targeted preparation of highly efficient lithium extractants based on 14-membered crown ethers // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 670-671.
GOST all authors (up to 50) Copy
Nesterov S. V., Zakurdaeva O. A. Targeted preparation of highly efficient lithium extractants based on 14-membered crown ethers // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 670-671.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2022.09.034
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.034
TI - Targeted preparation of highly efficient lithium extractants based on 14-membered crown ethers
T2 - Mendeleev Communications
AU - Nesterov, Sergey Vladimirovich
AU - Zakurdaeva, Olga Anatol'evna
PY - 2022
DA - 2022/09/05
PB - Mendeleev Communications
SP - 670-671
IS - 5
VL - 32
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2022_Nesterov,
author = {Sergey Vladimirovich Nesterov and Olga Anatol'evna Zakurdaeva},
title = {Targeted preparation of highly efficient lithium extractants based on 14-membered crown ethers},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.034},
number = {5},
pages = {670--671},
doi = {10.1016/j.mencom.2022.09.034}
}
MLA
Cite this
MLA Copy
Nesterov, Sergey Vladimirovich, and Olga Anatol'evna Zakurdaeva. “Targeted preparation of highly efficient lithium extractants based on 14-membered crown ethers.” Mendeleev Communications, vol. 32, no. 5, Sep. 2022, pp. 670-671. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.034.

Keywords

14-membered macrocycle
crown ether
distribution coefficient
extraction
lithium

Abstract

Modification of benzene rings in dibenzo-14-crown-4 by hydrogenation of a cyclohexane moiety or introduction of tert-butyl substituents leads to macrocycles superior to benzo-15-crown-5 in extraction of lithium salts from aqueous solutions and in resistance to leaching into the aqueous phase.

References

1.
Kulova T.L., Gavrilin I.M., Kudryashova Y.O., Skundin A.M.
Mendeleev Communications, 2020
2.
Ion-Pair Formation Constants of Lithium Borate and Lithium Hydroxide under Pressurized Water Nuclear Reactor Coolant Conditions
Ferguson J.P., Arcis H., Zimmerman G.H., Tremaine P.R.
Industrial & Engineering Chemistry Research, 2017
5.
Liquid-liquid extraction of lithium using lipophilic dibenzo-14-crown-4 ether carboxylic acid in hydrophobic room temperature ionic liquid
Torrejos R.E., Nisola G.M., Song H.S., Han J.W., Lawagon C.P., Seo J.G., Koo S., Kim H., Chung W.
Hydrometallurgy, 2016
6.
Lithium Isotope Separation by Liquid-Liquid Extraction Using Benzo-15-Crown-5
NISHIZAWA K., ISHINO S., WATANABE H., SHINAGAWA M.
Journal of Nuclear Science and Technology, 1984
7.
Theoretical prediction of 6Li/7Li separation in solvent extraction system using Urey model
Cui L., Yang X., Wang J., He H., Guo Y., Cheng F., Zhang S.
Chemical Engineering Journal, 2019
8.
An efficient synthesis of lithium-selective extractants: Tertiary-alkyl-14-crown-4 ethers
Sachleben R.A., Davis M.C., Bruce J.J., Ripple E.S., Driver J.L., Moyer B.A.
Tetrahedron Letters, 1993
9.
Behavior of Na and K in the extraction process of lithium isotope separation
Kostikova G.V., Maltseva I.E., Krasnova O.G., Shokurova N.A., Zhilov V.I.
Russian Chemical Bulletin, 2018
11.
Distribution of benzo-substituted crown-ethers between chloroform and water: effects of macrocycle ring size and lithium chloride
Zakurdaeva O.A., Asachenko A.F., Topchiy M.A., Nesterov S.V.
Journal of Radioanalytical and Nuclear Chemistry, 2018
12.
Theoretical and extraction studies on the selectivity of lithium with 14C4 derivatives
Chen W., Tian Y., Hu C., Zhao Z., Xu L., Tong B.
New Journal of Chemistry, 2020
13.
Cyclic polyethers and their complexes with metal salts
Pedersen C.J.
Journal of the American Chemical Society, 1967
14.
Benzo-cis-cyclohexano-14-crown-4 and its lithium thiocyanate complex
Bryan J.C., Sachleben R.A.
Acta Crystallographica Section C Crystal Structure Communications, 2000
15.
10.1016/j.mencom.2022.09.034_b0075
Zakurdaeva
J. Radioanal. Nucl. Chem., 2015