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Effect of the comonomer addition sequence in the synthesis of an acrylonitrile terpolymer on the solution rheology and fiber properties

, 
Lydia Alexandrovna Varfolomeeva 1
Lydia Alexandrovna Varfolomeeva
, 
Mikhail Sergeevich Kuzin 1
Mikhail Sergeevich Kuzin
, 
Andrey Fedorovich Vashchenko 1
Andrey Fedorovich Vashchenko
, 
Elena Vyacheslavna Chernikova 1, 2
Elena Vyacheslavna Chernikova
, 
Roman Vladimirovich Toms 1, 3
Roman Vladimirovich Toms
, 
Valerii Grigor'evich Kulichikhin 1
Valerii Grigor'evich Kulichikhin
10.1016/j.mencom.2022.09.028
Published 2022-09-05
Communication , Volume 32, Issue 5, 652-654
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Skvortsov I. Y. et al. Effect of the comonomer addition sequence in the synthesis of an acrylonitrile terpolymer on the solution rheology and fiber properties // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 652-654.
GOST all authors (up to 50) Copy
Skvortsov I. Y., Varfolomeeva L. A., Kuzin M. S., Vashchenko A. F., Chernikova E. V., Toms R. V., Kulichikhin V. G. Effect of the comonomer addition sequence in the synthesis of an acrylonitrile terpolymer on the solution rheology and fiber properties // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 652-654.
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TY - JOUR
DO - 10.1016/j.mencom.2022.09.028
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.028
TI - Effect of the comonomer addition sequence in the synthesis of an acrylonitrile terpolymer on the solution rheology and fiber properties
T2 - Mendeleev Communications
AU - Skvortsov, Ivan Yurievich
AU - Varfolomeeva, Lydia Alexandrovna
AU - Kuzin, Mikhail Sergeevich
AU - Vashchenko, Andrey Fedorovich
AU - Chernikova, Elena Vyacheslavna
AU - Toms, Roman Vladimirovich
AU - Kulichikhin, Valerii Grigor'evich
PY - 2022
DA - 2022/09/05
PB - Mendeleev Communications
SP - 652-654
IS - 5
VL - 32
ER -
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@article{2022_Skvortsov,
author = {Ivan Yurievich Skvortsov and Lydia Alexandrovna Varfolomeeva and Mikhail Sergeevich Kuzin and Andrey Fedorovich Vashchenko and Elena Vyacheslavna Chernikova and Roman Vladimirovich Toms and Valerii Grigor'evich Kulichikhin},
title = {Effect of the comonomer addition sequence in the synthesis of an acrylonitrile terpolymer on the solution rheology and fiber properties},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.028},
number = {5},
pages = {652--654},
doi = {10.1016/j.mencom.2022.09.028}
}
MLA
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Skvortsov, Ivan Yurievich, et al. “Effect of the comonomer addition sequence in the synthesis of an acrylonitrile terpolymer on the solution rheology and fiber properties.” Mendeleev Communications, vol. 32, no. 5, Sep. 2022, pp. 652-654. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.028.

Keywords

comonomer sequence
fiber spinning
polyacrylonitrile
reversible addition–fragmentation chain-transfer polymerization
rheology

Abstract

Polyacrylonitrile terpolymers based on acrylonitrile, acrylic acid, and methyl acrylate were synthesized by reversible addition–fragmentation chain-transfer polymerization with varying the monomer addition sequence during the synthesis. The monomer introduction sequence in the synthesis of a ternary copolymer significantly affects both the rheological properties of solutions and the strength of obtained fibers.

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