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1D CuI coordination polymers based on triphenylarsine and N,N'-ditopic co-ligands: synthesis, crystal structure and TADF properties

Yan Vladislavovich Demyanov 1
Yan Vladislavovich Demyanov
, 
Mariana Ivanovna Rakhmanova 1
Mariana Ivanovna Rakhmanova
, 
Irina Yur'evna Bagryanskaya 2
Irina Yur'evna Bagryanskaya
, 
Alexandr Viktorovich Artem’ev 1
Alexandr Viktorovich Artem’ev
10.1016/j.mencom.2022.09.027
Published 2022-09-05
Communication , Volume 32, Issue 5, 649-651
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Demyanov Y. V. et al. 1D CuI coordination polymers based on triphenylarsine and N,N'-ditopic co-ligands: synthesis, crystal structure and TADF properties // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 649-651.
GOST all authors (up to 50) Copy
Demyanov Y. V., Rakhmanova M. I., Bagryanskaya I. Y., Artem’ev A. V. 1D CuI coordination polymers based on triphenylarsine and N,N'-ditopic co-ligands: synthesis, crystal structure and TADF properties // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 649-651.
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TY - JOUR
DO - 10.1016/j.mencom.2022.09.027
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.027
TI - 1D CuI coordination polymers based on triphenylarsine and N,N'-ditopic co-ligands: synthesis, crystal structure and TADF properties
T2 - Mendeleev Communications
AU - Demyanov, Yan Vladislavovich
AU - Rakhmanova, Mariana Ivanovna
AU - Bagryanskaya, Irina Yur'evna
AU - Artem’ev, Alexandr Viktorovich
PY - 2022
DA - 2022/09/05
PB - Mendeleev Communications
SP - 649-651
IS - 5
VL - 32
ER -
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@article{2022_Demyanov,
author = {Yan Vladislavovich Demyanov and Mariana Ivanovna Rakhmanova and Irina Yur'evna Bagryanskaya and Alexandr Viktorovich Artem’ev},
title = {1D CuI coordination polymers based on triphenylarsine and N,N'-ditopic co-ligands: synthesis, crystal structure and TADF properties},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.027},
number = {5},
pages = {649--651},
doi = {10.1016/j.mencom.2022.09.027}
}
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Demyanov, Yan Vladislavovich, et al. “1D CuI coordination polymers based on triphenylarsine and N,N'-ditopic co-ligands: synthesis, crystal structure and TADF properties.” Mendeleev Communications, vol. 32, no. 5, Sep. 2022, pp. 649-651. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.027.

Keywords

coordination polymers
copper(I) iodide
photoluminescence
thermally activated delayed fluorescence
triphenylarsine

Abstract

1D coordination polymers [Cu2I2(AsPh3)2(L)]n (L = 4,4'-bi-pyridine, pyrazine) were synthesized via the reaction of CuI with AsPh3 and N,N'-ditopic co-ligand s L. At ambient temperature, these polymers exhibit short-lived (2.3–3.2 μs) thermally activated delayed fluorescence (TADF) with max at 530 nm (L = 4,4'-bipyridine) and 605 nm (L = pyrazine) and quantum efficiency up to 45%.

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