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Thermal rearrangement of bis(hydroxymethyl)phosphines as a way to P-chiral phosphine oxides

Irina Rishatovna Dayanova 1
Irina Rishatovna Dayanova
, 
Alexey Valer'evich Kurenkov 1
Alexey Valer'evich Kurenkov
, 
Kamil Dinarovich Akhmadgaleev 1, 2
Kamil Dinarovich Akhmadgaleev
, 
Kamila Ruslanovna Trigulova 1
Kamila Ruslanovna Trigulova
, 
Daut Rinatovich Islamov 3
Daut Rinatovich Islamov
, 
Olga Evgenievna Naumova 1
Olga Evgenievna Naumova
, 
Igor Dmitrievich Strelnik 1, 2
Igor Dmitrievich Strelnik
, 
Èlvira Ilgizovna Musina 1
Èlvira Ilgizovna Musina
, 
Andrey Anatol'evich Karasik 1
Andrey Anatol'evich Karasik
10.1016/j.mencom.2022.09.017
Published 2022-09-05
Communication , Volume 32, Issue 5, 622-623
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Dayanova I. R. et al. Thermal rearrangement of bis(hydroxymethyl)phosphines as a way to P-chiral phosphine oxides // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 622-623.
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Dayanova I. R., Kurenkov A. V., Akhmadgaleev K. D., Trigulova K. R., Islamov D. R., Naumova O. E., Strelnik I. D., Musina È. I., Karasik A. A. Thermal rearrangement of bis(hydroxymethyl)phosphines as a way to P-chiral phosphine oxides // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 622-623.
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TY - JOUR
DO - 10.1016/j.mencom.2022.09.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.017
TI - Thermal rearrangement of bis(hydroxymethyl)phosphines as a way to P-chiral phosphine oxides
T2 - Mendeleev Communications
AU - Dayanova, Irina Rishatovna
AU - Kurenkov, Alexey Valer'evich
AU - Akhmadgaleev, Kamil Dinarovich
AU - Trigulova, Kamila Ruslanovna
AU - Islamov, Daut Rinatovich
AU - Naumova, Olga Evgenievna
AU - Strelnik, Igor Dmitrievich
AU - Musina, Èlvira Ilgizovna
AU - Karasik, Andrey Anatol'evich
PY - 2022
DA - 2022/09/05
PB - Mendeleev Communications
SP - 622-623
IS - 5
VL - 32
ER -
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@article{2022_Dayanova,
author = {Irina Rishatovna Dayanova and Alexey Valer'evich Kurenkov and Kamil Dinarovich Akhmadgaleev and Kamila Ruslanovna Trigulova and Daut Rinatovich Islamov and Olga Evgenievna Naumova and Igor Dmitrievich Strelnik and Èlvira Ilgizovna Musina and Andrey Anatol'evich Karasik},
title = {Thermal rearrangement of bis(hydroxymethyl)phosphines as a way to P-chiral phosphine oxides},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.017},
number = {5},
pages = {622--623},
doi = {10.1016/j.mencom.2022.09.017}
}
MLA
Cite this
MLA Copy
Dayanova, Irina Rishatovna, et al. “Thermal rearrangement of bis(hydroxymethyl)phosphines as a way to P-chiral phosphine oxides.” Mendeleev Communications, vol. 32, no. 5, Sep. 2022, pp. 622-623. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.017.

Keywords

bis(hydroxymethyl)phosphines
chiral phosphine oxides
P-chirality
primary phosphines
rearrangement

Abstract

Bis(hydroxymethyl)(2-pyridyl)- and bis(hydroxymethyl)-[(2-pyridyl)ethyl]phosphines on heating to 180 °C undergorearrangement leading to racemic P-chiral tertiary P-methyl-P-(hydroxymethyl)-containing phosphine oxides. The spontaneous self-resolution of these enantiomer mixtures during the crystallization was demonstrated.

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