Home / Publications / Simultaneous formation of P–C/P–O-cage phosphoranes in the reaction of 2-[(2-methylcarbonyl)phenyloxy]-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane with hexafluoroacetone

Simultaneous formation of P–C/P–O-cage phosphoranes in the reaction of 2-[(2-methylcarbonyl)phenyloxy]-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane with hexafluoroacetone

, 
Mudaris Nurgaleevich Dimukhametov 1
Mudaris Nurgaleevich Dimukhametov
, 
Igor Anatol'evich Litvinov 1
Igor Anatol'evich Litvinov
, 
Aidar Timergalievich Gubaidullin 1
Aidar Timergalievich Gubaidullin
10.1016/j.mencom.2022.09.015
Published 2022-09-05
Communication , Volume 32, Issue 5, 615-618
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Mironov V. F. et al. Simultaneous formation of P–C/P–O-cage phosphoranes in the reaction of 2-[(2-methylcarbonyl)phenyloxy]-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane with hexafluoroacetone // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 615-618.
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Mironov V. F., Dimukhametov M. N., Litvinov I. A., Gubaidullin A. T. Simultaneous formation of P–C/P–O-cage phosphoranes in the reaction of 2-[(2-methylcarbonyl)phenyloxy]-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane with hexafluoroacetone // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 615-618.
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TY - JOUR
DO - 10.1016/j.mencom.2022.09.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.015
TI - Simultaneous formation of P–C/P–O-cage phosphoranes in the reaction of 2-[(2-methylcarbonyl)phenyloxy]-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane with hexafluoroacetone
T2 - Mendeleev Communications
AU - Mironov, Vladimir Fedorovich
AU - Dimukhametov, Mudaris Nurgaleevich
AU - Litvinov, Igor Anatol'evich
AU - Gubaidullin, Aidar Timergalievich
PY - 2022
DA - 2022/09/05
PB - Mendeleev Communications
SP - 615-618
IS - 5
VL - 32
ER -
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@article{2022_Mironov,
author = {Vladimir Fedorovich Mironov and Mudaris Nurgaleevich Dimukhametov and Igor Anatol'evich Litvinov and Aidar Timergalievich Gubaidullin},
title = {Simultaneous formation of P–C/P–O-cage phosphoranes in the reaction of 2-[(2-methylcarbonyl)phenyloxy]-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane with hexafluoroacetone},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.015},
number = {5},
pages = {615--618},
doi = {10.1016/j.mencom.2022.09.015}
}
MLA
Cite this
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Mironov, Vladimir Fedorovich, et al. “Simultaneous formation of P–C/P–O-cage phosphoranes in the reaction of 2-[(2-methylcarbonyl)phenyloxy]-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane with hexafluoroacetone.” Mendeleev Communications, vol. 32, no. 5, Sep. 2022, pp. 615-618. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.015.

Keywords

1,3,2-dioxaphospholanes
aldol reaction
cage phosphoranes
hexafluoroacetone
PCO/POC-rearrangement
spirophosphoranes

Abstract

Reaction of 2-[(2-methylcarbonyl)phenyloxy]-4,4,5,5-tetra-methyl-1,3,2-dioxaphospholane with hexafluoroacetone leads to the simultaneous formation of two P–C/P–O-cage phosphoranes. The P–C-cage species does not convert to the P–O-cage one neither under the kinetically (3 years, 20–25 °C, dichloromethane) nor under the thermo-dynamically controlled conditions (110 °C, toluene, 8 h).

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