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Effect of pressure on the low-temperature reaction of ethylene with N2O4

Nikolai Nikolaevich Tolkachev 1
Nikolai Nikolaevich Tolkachev
, 
Evgeny Nikiforovich Khodot 1
Evgeny Nikiforovich Khodot
, 
Iosif Izrailevich Lischiner 2
Iosif Izrailevich Lischiner
, 
Olga Vasil'evna Malova 2
Olga Vasil'evna Malova
, 
Vladimir Alexandrovich Tartakovsky 1
Vladimir Alexandrovich Tartakovsky
, 
Valérie Naudet 3
Valérie Naudet
10.1016/j.mencom.2022.09.009
Published 2022-09-05
Communication , Volume 32, Issue 5, 597-600
3
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Tolkachev N. N. et al. Effect of pressure on the low-temperature reaction of ethylene with N2O4 // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 597-600.
GOST all authors (up to 50) Copy
Tolkachev N. N., Khodot E. N., Lischiner I. I., Malova O. V., Tartakovsky V. A., Naudet V. Effect of pressure on the low-temperature reaction of ethylene with N2O4 // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 597-600.
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TY - JOUR
DO - 10.1016/j.mencom.2022.09.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.009
TI - Effect of pressure on the low-temperature reaction of ethylene with N2O4
T2 - Mendeleev Communications
AU - Tolkachev, Nikolai Nikolaevich
AU - Khodot, Evgeny Nikiforovich
AU - Lischiner, Iosif Izrailevich
AU - Malova, Olga Vasil'evna
AU - Tartakovsky, Vladimir Alexandrovich
AU - Naudet, Valérie
PY - 2022
DA - 2022/09/05
PB - Mendeleev Communications
SP - 597-600
IS - 5
VL - 32
ER -
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@article{2022_Tolkachev,
author = {Nikolai Nikolaevich Tolkachev and Evgeny Nikiforovich Khodot and Iosif Izrailevich Lischiner and Olga Vasil'evna Malova and Vladimir Alexandrovich Tartakovsky and Valérie Naudet},
title = {Effect of pressure on the low-temperature reaction of ethylene with N2O4},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.009},
number = {5},
pages = {597--600},
doi = {10.1016/j.mencom.2022.09.009}
}
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Tolkachev, Nikolai Nikolaevich, et al. “Effect of pressure on the low-temperature reaction of ethylene with N2O4.” Mendeleev Communications, vol. 32, no. 5, Sep. 2022, pp. 597-600. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.009.

Keywords

ambient heating
ethylene
low temperature reactions
nitro compounds
nitrogen tetroxide
pressure effect

Abstract

Calorimetric monitoring of the autoclave reaction N2O4 + C2H4 at –85 to +10 °C under argon pressure 10–30 bar revealed that the exothermic chemical reaction started at temperatures above –52 °C at 10 bar, whereas an intensive exothermic reaction started at –85 °C and pressure of 30 bar. IR study showed that oligo/polynitroethylene was formed at 30 bar, while carbonyl and hydroxy compound as well as nitrate R–ONO2 formation occurred upon processing at 10 bar.

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