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Reactions of ytterbium and magnesium gallylene complexes with carbon dioxide and diphenylketene

Vladimir Alexseyevich Dodonov 1
Vladimir Alexseyevich Dodonov
, 
Alexandra Anatol'evna Skatova 1
Alexandra Anatol'evna Skatova
, 
Igor Leonidovich Fedushkin 1
Igor Leonidovich Fedushkin
10.1016/j.mencom.2022.09.004
Published 2022-09-05
Communication , Volume 32, Issue 5, 582-584
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Dodonov V. A., Skatova A. A., Fedushkin I. L. Reactions of ytterbium and magnesium gallylene complexes with carbon dioxide and diphenylketene // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 582-584.
GOST all authors (up to 50) Copy
Dodonov V. A., Skatova A. A., Fedushkin I. L. Reactions of ytterbium and magnesium gallylene complexes with carbon dioxide and diphenylketene // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 582-584.
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TY - JOUR
DO - 10.1016/j.mencom.2022.09.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.004
TI - Reactions of ytterbium and magnesium gallylene complexes with carbon dioxide and diphenylketene
T2 - Mendeleev Communications
AU - Dodonov, Vladimir Alexseyevich
AU - Skatova, Alexandra Anatol'evna
AU - Fedushkin, Igor Leonidovich
PY - 2022
DA - 2022/09/05
PB - Mendeleev Communications
SP - 582-584
IS - 5
VL - 32
ER -
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@article{2022_Dodonov,
author = {Vladimir Alexseyevich Dodonov and Alexandra Anatol'evna Skatova and Igor Leonidovich Fedushkin},
title = {Reactions of ytterbium and magnesium gallylene complexes with carbon dioxide and diphenylketene},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.004},
number = {5},
pages = {582--584},
doi = {10.1016/j.mencom.2022.09.004}
}
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Dodonov, Vladimir Alexseyevich, et al. “Reactions of ytterbium and magnesium gallylene complexes with carbon dioxide and diphenylketene.” Mendeleev Communications, vol. 32, no. 5, Sep. 2022, pp. 582-584. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.004.

Keywords

carbon dioxide
cycloaddition
gallylenes
ketenes
magnesium
non-innocent α-diimine ligands
X-ray diffraction
ytterbium

Abstract

Reactivity of ytterbium and magnesium complexes of gallylenes against carbon dioxide and diphenylketene has been assessed. Ytterbium complex of redox-active gallylene [{(dpp-bian)Ga}2Yb(DME)2] (dpp-bian = 1,2-bis[(2,6-diiso-propylphenyl)imino]acenaphthene) on treatment with CO2 gives complex [(dpp-bian)Ga(DME)Me], while the treatment of magnesium-stabilized gallylene[{(dpp-bian)Ga}2Mg(DME)2] with Ph2CCO affords cycloadduct [(dpp-bian)(Ph2CCO)GaMe].

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