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Synthesis, structure and catalytic properties of Pdii-based bimetallic complexes with ferrocenecarboxylic acid

Anna Sergeevna Popova 1, 2
Anna Sergeevna Popova
, 
Nadezhda K Ogarkova 2
Nadezhda K Ogarkova
,  , 
Ivan Vladimirovich Skabitsky 1
Ivan Vladimirovich Skabitsky
, 
Ekaterina Konstantinovna Kultyshkina 2
Ekaterina Konstantinovna Kultyshkina
, 
Ilya Arkad'evich Yakushev 1
Ilya Arkad'evich Yakushev
, 
Michael Natanovich Vargaftik 1
Michael Natanovich Vargaftik
10.1016/j.mencom.2022.09.002
Published 2022-09-05
Communication , Volume 32, Issue 5, 576-578
5
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Popova A. S. et al. Synthesis, structure and catalytic properties of Pdii-based bimetallic complexes with ferrocenecarboxylic acid // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 576-578.
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Popova A. S., Ogarkova N. K., Shapovalov S. S., Skabitsky I. V., Kultyshkina E. K., Yakushev I. A., Vargaftik M. N. Synthesis, structure and catalytic properties of Pdii-based bimetallic complexes with ferrocenecarboxylic acid // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 576-578.
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TY - JOUR
DO - 10.1016/j.mencom.2022.09.002
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.002
TI - Synthesis, structure and catalytic properties of Pdii-based bimetallic complexes with ferrocenecarboxylic acid
T2 - Mendeleev Communications
AU - Popova, Anna Sergeevna
AU - Ogarkova, Nadezhda K
AU - Shapovalov, Sergey Sergeevich
AU - Skabitsky, Ivan Vladimirovich
AU - Kultyshkina, Ekaterina Konstantinovna
AU - Yakushev, Ilya Arkad'evich
AU - Vargaftik, Michael Natanovich
PY - 2022
DA - 2022/09/05
PB - Mendeleev Communications
SP - 576-578
IS - 5
VL - 32
ER -
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@article{2022_Popova,
author = {Anna Sergeevna Popova and Nadezhda K Ogarkova and Sergey Sergeevich Shapovalov and Ivan Vladimirovich Skabitsky and Ekaterina Konstantinovna Kultyshkina and Ilya Arkad'evich Yakushev and Michael Natanovich Vargaftik},
title = {Synthesis, structure and catalytic properties of Pdii-based bimetallic complexes with ferrocenecarboxylic acid},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.002},
number = {5},
pages = {576--578},
doi = {10.1016/j.mencom.2022.09.002}
}
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Popova, Anna Sergeevna, et al. “Synthesis, structure and catalytic properties of Pdii-based bimetallic complexes with ferrocenecarboxylic acid.” Mendeleev Communications, vol. 32, no. 5, Sep. 2022, pp. 576-578. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.002.

Keywords

e]pentalene
dibenzo[a
diphenylacetylene
ferrocenecarboxylic acid
homogeneous catalysis
ligand exchange
Palladium complexes
XRD analysis

Abstract

Novel highly soluble palladium-based complexes with ferrocenecarboxylic acid of general formula [Pd(lut)2(FcCOO)2] (lut is 2,6-or 3,4-lutidines) were synthesized and structurally characterized by single-crystal X-ray diffraction. The catalytic oxidation of 1,2-diphenyl-acetylene with these complexes gave dibenzo[a,e]pentalene derivative along with other products.

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