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The purity of SnCl4 as monitored by 35Cl nuclear quadrupole resonance

Eleonora Aleksandrovna Kravchenko 1
Eleonora Aleksandrovna Kravchenko
, 
Andrei Andreevich Gippius 2, 3
Andrei Andreevich Gippius
, 
Aleksei Vladimirovich Tkachev 2
Aleksei Vladimirovich Tkachev
, 
Maxim Valeryevich Mastryukov 1
Maxim Valeryevich Mastryukov
, 
10.1016/j.mencom.2022.07.044
Published 2022-07-01
Communication , Volume 32, Issue 4, 567-569
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Kravchenko E. A. et al. The purity of SnCl4 as monitored by 35Cl nuclear quadrupole resonance // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 567-569.
GOST all authors (up to 50) Copy
Kravchenko E. A., Gippius A. A., Tkachev A. V., Mastryukov M. V., Brekhovskikh M. N. The purity of SnCl4 as monitored by 35Cl nuclear quadrupole resonance // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 567-569.
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TY - JOUR
DO - 10.1016/j.mencom.2022.07.044
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.044
TI - The purity of SnCl4 as monitored by 35Cl nuclear quadrupole resonance
T2 - Mendeleev Communications
AU - Kravchenko, Eleonora Aleksandrovna
AU - Gippius, Andrei Andreevich
AU - Tkachev, Aleksei Vladimirovich
AU - Mastryukov, Maxim Valeryevich
AU - Brekhovskikh, Maria Nikolaevna
PY - 2022
DA - 2022/07/01
PB - Mendeleev Communications
SP - 567-569
IS - 4
VL - 32
ER -
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@article{2022_Kravchenko,
author = {Eleonora Aleksandrovna Kravchenko and Andrei Andreevich Gippius and Aleksei Vladimirovich Tkachev and Maxim Valeryevich Mastryukov and Maria Nikolaevna Brekhovskikh},
title = {The purity of SnCl4 as monitored by 35Cl nuclear quadrupole resonance},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.044},
number = {4},
pages = {567--569},
doi = {10.1016/j.mencom.2022.07.044}
}
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Kravchenko, Eleonora Aleksandrovna, et al. “The purity of SnCl4 as monitored by 35Cl nuclear quadrupole resonance.” Mendeleev Communications, vol. 32, no. 4, Jul. 2022, pp. 567-569. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.044.

Keywords

impurities
mass spectrometry
nuclear quadrupole resonance
purification
tin chloride

Abstract

The nuclear quadrupole resonance (NQR) spectroscopy was used to control the comparative purity of three SnCl4 samples subjected to successive stages of deep purification. The results showed that at 77 K the samples were identical in purity degree due to the ‘freezing’ of impurities into a separate fraction not affecting the perfection of the SnCl4 crystal lattice. The results of relaxation measurements suggest that paramagnetic impurity atoms (Fe and Cr) contained in the samples in small amounts might be embedded into the crystal lattice causing extremely long spin–spin relaxation time.

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