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Synthesis and properties of dicationic ionic liquids with pentasiloxane linker

Vladimir Georgievich Krasovskiy 1
Vladimir Georgievich Krasovskiy
Olga Borisovna Gorbatsevich 2
Olga Borisovna Gorbatsevich
Evgenia Victorovna Talalaeva 2
Evgenia Victorovna Talalaeva
Lev Mikhailovich Glukhov 1
Lev Mikhailovich Glukhov
Elena Aleksandrovna Chernikova 1
Elena Aleksandrovna Chernikova
Leonid Modestovich Kustov
Published 2022-07-01
CommunicationVolume 32, Issue 4, 551-553
4
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Krasovskiy V. G. et al. Synthesis and properties of dicationic ionic liquids with pentasiloxane linker // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 551-553.
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Krasovskiy V. G., Gorbatsevich O. B., Talalaeva E. V., Glukhov L. M., Chernikova E. A., Kustov L. M. Synthesis and properties of dicationic ionic liquids with pentasiloxane linker // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 551-553.
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TY - JOUR
DO - 10.1016/j.mencom.2022.07.039
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.039
TI - Synthesis and properties of dicationic ionic liquids with pentasiloxane linker
T2 - Mendeleev Communications
AU - Krasovskiy, Vladimir Georgievich
AU - Gorbatsevich, Olga Borisovna
AU - Talalaeva, Evgenia Victorovna
AU - Glukhov, Lev Mikhailovich
AU - Chernikova, Elena Aleksandrovna
AU - Kustov, Leonid Modestovich
PY - 2022
DA - 2022/07/01
PB - Mendeleev Communications
SP - 551-553
IS - 4
VL - 32
ER -
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@article{2022_Krasovskiy,
author = {Vladimir Georgievich Krasovskiy and Olga Borisovna Gorbatsevich and Evgenia Victorovna Talalaeva and Lev Mikhailovich Glukhov and Elena Aleksandrovna Chernikova and Leonid Modestovich Kustov},
title = {Synthesis and properties of dicationic ionic liquids with pentasiloxane linker},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.039},
number = {4},
pages = {551--553},
doi = {10.1016/j.mencom.2022.07.039}
}
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Krasovskiy, Vladimir Georgievich, et al. “Synthesis and properties of dicationic ionic liquids with pentasiloxane linker.” Mendeleev Communications, vol. 32, no. 4, Jul. 2022, pp. 551-553. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.039.

Keywords

dicationic ionic liquids
hydrolytic stability
imidazolium compounds
pentasiloxane linker
thermal stability
viscosity

Abstract

New dicationic ionic liquids with pentasiloxane linker between two imidazolium moieties and bis(trifluoromethyl-sulfonyl)imide anions were synthesized; their melting points, glass transition temperatures and viscosities were measured, and thermal and hydrolytic stabilities were investigated. The dependence of the properties of these ionic liquids on the length of the siloxane linker in the cation part is revealed.

References

1.
P. Walden, Bull. L’Académie Impériale des Sci. St.-Pétersbourg, 1914, 8, 405.
3.
Industrial Applications of Ionic Liquids
Greer A.J., Jacquemin J., Hardacre C.
Molecules, 2020
4.
Prospects and Design Insights of Neat Ionic Liquids as Supercapacitor Electrolytes
Lethesh K.C., Bamgbopa M.O., Susantyoko R.A.
Frontiers in Energy Research, 2021
5.
Ionic liquids: “normal” solvents or nanostructured fluids?
Marullo S., D'Anna F., Rizzo C., Billeci F.
Organic and Biomolecular Chemistry, 2021
6.
Synthesis and Characterization of New Imidazolium Ionic Liquid Based Energetic Plasticizers
Miri A., Fareghi‐Alamdari R., Nikpour M., Hasanzadeh N.
Propellants, Explosives, Pyrotechnics, 2021
7.
Ionic Liquids as Performance Ingredients in Space Lubricants
Nyberg E., Schneidhofer C., Pisarova L., Dörr N., Minami I.
Molecules, 2021
8.
10.1016/j.mencom.2022.07.039_b0040
Nancarrow
ChemBioEng. Rev., 2017
9.
CO 2 Chemisorption Behavior of Coordination‐Derived Phenolate Sorbents
Suo X., Yang Z., Fu Y., Do‐Thanh C., Chen H., Luo H., Jiang D., Mahurin S.M., Xing H., Dai S.
ChemSusChem, 2021
10.
“Giant” Nitrogen Uptake in Ionic Liquids Confined in Carbon Pores
Harmanli I., Tarakina N.V., Antonietti M., Oschatz M.
Journal of the American Chemical Society, 2021
11.
Predicting the melting temperature and the heat of melting of ionic liquids
12.
Targeted modifications in ionic liquids – from understanding to design
Philippi F., Welton T.
Physical Chemistry Chemical Physics, 2021
13.
Antimicrobial Ionic Liquid‐Based Materials for Biomedical Applications
Nikfarjam N., Ghomi M., Agarwal T., Hassanpour M., Sharifi E., Khorsandi D., Ali Khan M., Rossi F., Rossetti A., Nazarzadeh Zare E., Rabiee N., Afshar D., Vosough M., Kumar Maiti T., Mattoli V., et. al.
Advanced Functional Materials, 2021
14.
10.1016/j.mencom.2022.07.039_b0070
Curreri
Adv., 2021
15.
The Emerging Role of Ionic Liquid-Based Approaches for Enhanced Skin Permeation of Bioactive Molecules: A Snapshot of the Past Couple of Years
16.
10.1016/j.mencom.2022.07.039_b0080
Wang
Polym. Degrad. Stab., 2021
17.
10.1016/j.mencom.2022.07.039_b0085
Protz
Carbohydr. Polym. Technol. Appl., 2021
18.
Screening Ionic Liquids for Dissolving a Melamine Formaldehyde Resin Prepolymer to Fabricate Flame-Retardant Fibers
Chen L., Liu X., Sun Y., Zhou L., Nie Y., Song K.
ACS Sustainable Chemistry and Engineering, 2020
19.
Microstructural and Dynamical Heterogeneities in Ionic Liquids
Wang Y., Li B., Sarman S., Mocci F., Lu Z., Yuan J., Laaksonen A., Fayer M.D.
Chemical Reviews, 2020
20.
Ion Dissociation in Ionic Liquids and Ionic Liquid Solutions
23.
Dicationic imidazolium-based dicarboxylate ionic liquids: Thermophysical properties and solubility
Kuhn B.L., Osmari B.F., Heinen T.M., Bonacorso H.G., Zanatta N., Nielsen S.O., Ranathunga D.T., Villetti M.A., Frizzo C.P.
Journal of Molecular Liquids, 2020
24.
Properties of Dicationic Disiloxane Ionic Liquids
Krasovskiy V.G., Kapustin G.I., Gorbatsevich O.B., Glukhov L.M., Chernikova E.A., Koroteev A.A., Kustov L.M.
Molecules, 2020
25.
Dicationic Ionic Liquids As Heat Transfer Fluids in Vacuum
Krasovskii V.G., Kapustin G.I., Glukhov L.M., Chernikova E.A., Kustov L.M.
Russian Journal of Physical Chemistry A, 2022
26.
Monosodiumoxyorganoalkoxysilanes: Synthesis and properties
Rebrov E.A., Muzafarov A.M.
Heteroatom Chemistry, 2006
27.
From the discovery of sodiumoxyorganoalkoxysilanes to the organosilicon dendrimers and back
Muzafarov A.M., Rebrov E.A.
Journal of Polymer Science, Part A: Polymer Chemistry, 2008
28.
The synthesis and characterisation of novel dimethyl- and diphenyl-silanediolates
Schamschurin A., Uhrig D., Fisher M., Clarke S., Matisons J.
Silicon Chemistry, 2008
30.
Sodiumoxy(aminopropyl)alkoxysilanes - AB2 type monomers for the synthesis of hyperbranched poly(aminopropyl)alkoxysiloxanes and their derivatives
Migulin D., Milenin S., Cherkaev G., Svidchenko E., Surin N., Muzafarov A.
Journal of Organometallic Chemistry, 2018
31.
Selective formation of 1,5-disodiumoxyhexamethyltrisiloxane in the reaction of dimethylsiloxanes and sodium hydroxide
Talalaeva E.V., Kalinina A.A., Vasilenko N.G., Demchenko N.V., Cherkaev G.V., Goloveshkin A.S., Muzafarov A.M.
Journal of Organometallic Chemistry, 2020
33.
Krasovskiy V.G., Kapustin G.I., Glukhov L.M., Gorbatsevich O.B., Chernikova E.A., Koroteev A.A., Kustov L.M.
Mendeleev Communications, 2020
34.
Dicationic disiloxane ionic liquids as heat transfer agents in vacuo
Krasovskiy V.G., Kapustin G.I., Gorbatsevich O.B., Glukhov L.M., Chernikova E.A., Koroteev A.A., Kustov L.M.
Russian Chemical Bulletin, 2021
35.
10.1016/j.mencom.2022.07.039_b0175
Comprehensive Organometallic Chemistry, 1982