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Synthesis and crystal structures of novel glycoluril carboxylic acids conglomerates

Vladimir Vladimirovich Baranov 1
Vladimir Vladimirovich Baranov
, 
Tatyana Nikolaevna Vol'khina 2, 3
Tatyana Nikolaevna Vol'khina
, 
Natal'ya Georgievna Kolotyrkina 1
Natal'ya Georgievna Kolotyrkina
, 
Angelina Nikolaevna Kravchenko 1
Angelina Nikolaevna Kravchenko
10.1016/j.mencom.2022.07.034
Published 2022-07-01
Communication , Volume 32, Issue 4, 537-539
6
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Baranov V. V. et al. Synthesis and crystal structures of novel glycoluril carboxylic acids conglomerates // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 537-539.
GOST all authors (up to 50) Copy
Baranov V. V., Vol'khina T. N., Kolotyrkina N. G., Kravchenko A. N. Synthesis and crystal structures of novel glycoluril carboxylic acids conglomerates // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 537-539.
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TY - JOUR
DO - 10.1016/j.mencom.2022.07.034
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.034
TI - Synthesis and crystal structures of novel glycoluril carboxylic acids conglomerates
T2 - Mendeleev Communications
AU - Baranov, Vladimir Vladimirovich
AU - Vol'khina, Tatyana Nikolaevna
AU - Kolotyrkina, Natal'ya Georgievna
AU - Kravchenko, Angelina Nikolaevna
PY - 2022
DA - 2022/07/01
PB - Mendeleev Communications
SP - 537-539
IS - 4
VL - 32
ER -
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@article{2022_Baranov,
author = {Vladimir Vladimirovich Baranov and Tatyana Nikolaevna Vol'khina and Natal'ya Georgievna Kolotyrkina and Angelina Nikolaevna Kravchenko},
title = {Synthesis and crystal structures of novel glycoluril carboxylic acids conglomerates},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.034},
number = {4},
pages = {537--539},
doi = {10.1016/j.mencom.2022.07.034}
}
MLA
Cite this
MLA Copy
Baranov, Vladimir Vladimirovich, et al. “Synthesis and crystal structures of novel glycoluril carboxylic acids conglomerates.” Mendeleev Communications, vol. 32, no. 4, Jul. 2022, pp. 537-539. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.034.

Keywords

45-dihydroxyimidazolidin-2-ones
carboxylic acids
conglomerats
crystal structures
crystallization
glycolurils
racemates
ureido acids

Abstract

The two novel conglomerates were obtained by crystallization of racemic (2'S,3aS,6aR)/(2'R,3aR,6aS) (glycoluril-1-yl)-3-methylbutanoic acid and (2'R,3aR,6aR)/(2'S,3aS,6aS) (4,6-dimethylglycoluril-1-yl)pentanoic acid synthesized by highly diastereoselective condensation of 4,5-dihydroxy- imidazolidin-2-ones with racemic ureido acids. The differences in the molecular geometry of synthesized racemates were studied by X-ray diffraction that showed them to crystallize as conglomerates in non-centrosymmetric space groups Pna21 and P212121, respectively

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