Home / Publications / Mobility of water molecules in Li+, Na+ and Cs+ ionic forms of Nafion membrane studied by NMR

Mobility of water molecules in Li+, Na+ and Cs+ ionic forms of Nafion membrane studied by NMR

Nikita Andreevich Slesarenko 1
Nikita Andreevich Slesarenko
, 
Alexander Vladimirovich Chernyak 1, 2
Alexander Vladimirovich Chernyak
,  , 
Vladimir Alekseevich Zabrodin 1
Vladimir Alekseevich Zabrodin
, 
Vitaly Ivanovich Volkov 1, 2
Vitaly Ivanovich Volkov
2 Scienific Center in Chernogolovka, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
10.1016/j.mencom.2022.07.033
Published 2022-07-01
Communication , Volume 32, Issue 4, 534-536
6
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Slesarenko N. A. et al. Mobility of water molecules in Li+, Na+ and Cs+ ionic forms of Nafion membrane studied by NMR // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 534-536.
GOST all authors (up to 50) Copy
Slesarenko N. A., Chernyak A. V., Avilova I. A., Zabrodin V. A., Volkov V. I. Mobility of water molecules in Li+, Na+ and Cs+ ionic forms of Nafion membrane studied by NMR // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 534-536.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2022.07.033
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.033
TI - Mobility of water molecules in Li+, Na+ and Cs+ ionic forms of Nafion membrane studied by NMR
T2 - Mendeleev Communications
AU - Slesarenko, Nikita Andreevich
AU - Chernyak, Alexander Vladimirovich
AU - Avilova, Irina Alekseevna
AU - Zabrodin, Vladimir Alekseevich
AU - Volkov, Vitaly Ivanovich
PY - 2022
DA - 2022/07/01
PB - Mendeleev Communications
SP - 534-536
IS - 4
VL - 32
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2022_Slesarenko,
author = {Nikita Andreevich Slesarenko and Alexander Vladimirovich Chernyak and Irina Alekseevna Avilova and Vladimir Alekseevich Zabrodin and Vitaly Ivanovich Volkov},
title = {Mobility of water molecules in Li+, Na+ and Cs+ ionic forms of Nafion membrane studied by NMR},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.033},
number = {4},
pages = {534--536},
doi = {10.1016/j.mencom.2022.07.033}
}
MLA
Cite this
MLA Copy
Slesarenko, Nikita Andreevich, et al. “Mobility of water molecules in Li+, Na+ and Cs+ ionic forms of Nafion membrane studied by NMR.” Mendeleev Communications, vol. 32, no. 4, Jul. 2022, pp. 534-536. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.033.

Keywords

1H NMR relaxation times
correlation time
hydration number
Nafion membrane
water diffusion

Abstract

Correlation times and diffusion coefficients of water molecules were measured for the first time by 1H spin relaxation and pulsed field gradient NMR in Li+, Na+ and Cs+ ionic forms of Nafion 117 membrane. Hydration numbers of Li+, Na+ and Cs+ cations were calculated. It was shown that at high humidity macroscopic transfer is controlled by the local translational motion of water molecules.

References

1.
Yaroslavtsev A.B., Stenina I.A.
Mendeleev Communications, 2021
2.
Modification of the mechanism of proton conductivity of the perfluorinated membrane copolymer by nanodiamonds
Kulvelis Y.V., Primachenko O.N., Gofman I.V., Odinokov A.S., Shvidchenko A.V., Yudina E.B., Marinenko E.A., Lebedev V.T., Vul A.Y.
Russian Chemical Bulletin, 2021
3.
NMR Parameters of Imidazolium Ionic Liquids as Indicators of Their State and Properties in Aqueous Solutions
Shahkhatuni A.A., Shahkhatuni A.G., Mamyan S.S., Ananikov V.P., Harutyunyan A.S.
Journal of Solution Chemistry, 2020
4.
"Solvent-in-salt" systems for design of new materials in chemistry, biology and energy research.
Azov V.A., Egorova K.S., Seitkalieva M.M., Kashin A.S., Ananikov V.P.
Chemical Society Reviews, 2018
6.
Water in Perfluorinated Sulfonic Acid Nafion Membranes
Iwamoto R., Oguro K., Sato M., Iseki Y.
Journal of Physical Chemistry B, 2002
8.
NMR Investigation of the Dynamics of Confined Water in Nafion-Based Electrolyte Membranes at Subfreezing Temperatures
Nicotera I., Coppola L., Rossi C.O., Youssry M., Ranieri G.A.
Journal of Physical Chemistry B, 2009
9.
NMR and Pulsed Field Gradient NMR Approach of Water Sorption Properties in Nafion at Low Temperature
Guillermo A., Gebel G., Mendil-Jakani H., Pinton E.
Journal of Physical Chemistry B, 2009
10.
NMR studies of proton transport in fuel cell membranes at sub-freezing conditions
Ma Z., Jiang R., Myers M.E., Thompson E.L., Gittleman C.S.
Journal of Materials Chemistry A, 2011
13.
Comprehensive Picture of Water Dynamics in Nafion Membranes at Different Levels of Hydration
Hammer R., Schönhoff M., Hansen M.R.
Journal of Physical Chemistry B, 2019
15.
Hydration and Water Molecules Mobility in Acid Form of Nafion Membrane Studied by 1H NMR Techniques
Chernyak A.V., Vasiliev S.G., Avilova I.A., Volkov V.I.
Applied Magnetic Resonance, 2019
16.
Molecular and Ionic Diffusion in Ion Exchange Membranes and Biological Systems (Cells and Proteins) Studied by NMR
Volkov V.I., Chernyak A.V., Avilova I.A., Slesarenko N.A., Melnikova D.L., Skirda V.D.
Membranes, 2021
18.
Water behavior in perfluorinated ion-exchange membranes
Volkov V.I., Vasilyak S.L., Park I.-., Kim H.J., Ju H., Volkov E.V., Choh S.H.
Applied Magnetic Resonance, 2003
20.
Mobility of Cations and Water Molecules in Sulfocation-Exchange Membranes Based on Polyethylene and Sulfonated Grafted Polystyrene
Volkov V.I., Chernyak A.V., Golubenko D.V., Shevlyakova N.V., Tverskoy V.A., Yaroslavtsev A.B.
Membranes and Membrane Technologies, 2020
21.
Golubenko D.V., Safronova E.Y., Ilyin A.B., Shevlyakov N.V., Tverskoi V.A., Pourcelly G., Yaroslavtsev A.B.
Mendeleev Communications, 2017