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Synthesis and photovoltaic properties of novel (X-DADAD)n conjugated polymers with fluorene and phenylene blocks

,  , 
Vladimir Gennadievich Kurbatov 1
Vladimir Gennadievich Kurbatov
, 
Mikhail Vasilievich Klyuev 2
Mikhail Vasilievich Klyuev
, 
Alexander Vital'evich Akkuratov 1
Alexander Vital'evich Akkuratov
10.1016/j.mencom.2022.07.031
Published 2022-07-01
Communication , Volume 32, Issue 4, 527-530
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Kuznetsov I. E. et al. Synthesis and photovoltaic properties of novel (X-DADAD)n conjugated polymers with fluorene and phenylene blocks // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 527-530.
GOST all authors (up to 50) Copy
Kuznetsov I. E., Sideltsev M. E., Kurbatov V. G., Klyuev M. V., Akkuratov A. V. Synthesis and photovoltaic properties of novel (X-DADAD)n conjugated polymers with fluorene and phenylene blocks // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 527-530.
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TY - JOUR
DO - 10.1016/j.mencom.2022.07.031
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.031
TI - Synthesis and photovoltaic properties of novel (X-DADAD)n conjugated polymers with fluorene and phenylene blocks
T2 - Mendeleev Communications
AU - Kuznetsov, Iliya Evgen'evich
AU - Sideltsev, Maxim Evgen'evich
AU - Kurbatov, Vladimir Gennadievich
AU - Klyuev, Mikhail Vasilievich
AU - Akkuratov, Alexander Vital'evich
PY - 2022
DA - 2022/07/01
PB - Mendeleev Communications
SP - 527-530
IS - 4
VL - 32
ER -
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@article{2022_Kuznetsov,
author = {Iliya Evgen'evich Kuznetsov and Maxim Evgen'evich Sideltsev and Vladimir Gennadievich Kurbatov and Mikhail Vasilievich Klyuev and Alexander Vital'evich Akkuratov},
title = {Synthesis and photovoltaic properties of novel (X-DADAD)n conjugated polymers with fluorene and phenylene blocks},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.031},
number = {4},
pages = {527--530},
doi = {10.1016/j.mencom.2022.07.031}
}
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Kuznetsov, Iliya Evgen'evich, et al. “Synthesis and photovoltaic properties of novel (X-DADAD)n conjugated polymers with fluorene and phenylene blocks.” Mendeleev Communications, vol. 32, no. 4, Jul. 2022, pp. 527-530. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.031.
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Keywords

benzothiadiazole
branched side chains
conjugated polymer
organic solar cells
thiophene

Abstract

Novel fluorene- and phenylene-based conjugated polymers with the TBTBT molecular framework consisting of the thiophene (T) and benzothiadiazole (B) building blocks have been synthesized and investigated. It has been demonstrated that the variation of X building blocks with branched side chains in (X-TBTBT)n-type structures, as well as the introduction of fluorine into the main chain, strongly affects the optical, electronic and physicochemical properties of the obtained polymers. The phenylene-based polymer with a fluorine- loaded TBTBT block achieves a power conversion efficiency of 7% in organic solar cells, which can be further improved by optimizing the active layer morphology.

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