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Isostructural hybrid iodometalate(III)/triiodide salts with perovskite-like packing: comparison of physical properties for SbIII and BiIII complexes

Nikita Alekseevich Korobeynikov 1
Nikita Alekseevich Korobeynikov
, 
Andrey Nikolaevich Usoltsev 1
Andrey Nikolaevich Usoltsev
, 
Taisiya Sergeevna Sukhikh 1
Taisiya Sergeevna Sukhikh
, 
Vladimir Ravilevich Shayapov 1
Vladimir Ravilevich Shayapov
, 
Maksim Nail'evich Sokolov 1
Maksim Nail'evich Sokolov
, 
Sergey Alexandrovich Adonin 1
Sergey Alexandrovich Adonin
10.1016/j.mencom.2022.07.028
Published 2022-07-01
Communication , Volume 32, Issue 4, 517-519
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Korobeynikov N. A. et al. Isostructural hybrid iodometalate(III)/triiodide salts with perovskite-like packing: comparison of physical properties for SbIII and BiIII complexes // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 517-519.
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Korobeynikov N. A., Usoltsev A. N., Sukhikh T. S., Shayapov V. R., Sokolov M. N., Adonin S. A. Isostructural hybrid iodometalate(III)/triiodide salts with perovskite-like packing: comparison of physical properties for SbIII and BiIII complexes // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 517-519.
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TY - JOUR
DO - 10.1016/j.mencom.2022.07.028
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.028
TI - Isostructural hybrid iodometalate(III)/triiodide salts with perovskite-like packing: comparison of physical properties for SbIII and BiIII complexes
T2 - Mendeleev Communications
AU - Korobeynikov, Nikita Alekseevich
AU - Usoltsev, Andrey Nikolaevich
AU - Sukhikh, Taisiya Sergeevna
AU - Shayapov, Vladimir Ravilevich
AU - Sokolov, Maksim Nail'evich
AU - Adonin, Sergey Alexandrovich
PY - 2022
DA - 2022/07/01
PB - Mendeleev Communications
SP - 517-519
IS - 4
VL - 32
ER -
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@article{2022_Korobeynikov,
author = {Nikita Alekseevich Korobeynikov and Andrey Nikolaevich Usoltsev and Taisiya Sergeevna Sukhikh and Vladimir Ravilevich Shayapov and Maksim Nail'evich Sokolov and Sergey Alexandrovich Adonin},
title = {Isostructural hybrid iodometalate(III)/triiodide salts with perovskite-like packing: comparison of physical properties for SbIII and BiIII complexes},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.028},
number = {4},
pages = {517--519},
doi = {10.1016/j.mencom.2022.07.028}
}
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Cite this
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Korobeynikov, Nikita Alekseevich, et al. “Isostructural hybrid iodometalate(III)/triiodide salts with perovskite-like packing: comparison of physical properties for SbIII and BiIII complexes.” Mendeleev Communications, vol. 32, no. 4, Jul. 2022, pp. 517-519. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.028.

Keywords

antimony
Bismuth
halide complexes
semiconductors
triiodides

Abstract

Reactions of Sb2O3 or Bi2O3, 1,2-bis(4-pyridyl)ethane (bpe) and diiodine in concentrated HI resulted in isostructural salts (H2bpe)2[MI6](I3) [M = Sb (1), Bi (2)] featuring perovskite-like arrangement of anions in crystal packing. Physical properties, including UV-Vis and Raman spectra, as well as thermal stability, were investigated and compared for this pair of complexes; the optical band gaps for 1 and 2 are 1.32 and 1.57 eV, respectively.

References

1.
Polynuclear halide complexes of Bi(III): From structural diversity to the new properties
Adonin S.A., Sokolov M.N., Fedin V.P.
Coordination Chemistry Reviews, 2016
4.
Iodobismuthate(III) and Iodobismuthate(III)/Iodocuprate(I) Complexes with Organic Ligands
Kelly A.W., Wheaton A.M., Nicholas A.D., Barnes F.H., Patterson H.H., Pike R.D.
European Journal of Inorganic Chemistry, 2017
5.
Alkyl Pyridinium Iodocuprate(I) Clusters: Structural Types and Charge Transfer Behavior
Wheaton A.M., Streep M.E., Ohlhaver C.M., Nicholas A.D., Barnes F.H., Patterson H.H., Pike R.D.
ACS Omega, 2018
6.
Bismuth compounds [Ph3BuP]+I−, [Ph3BuP] 2 + [Bi2I8 · 2Me2C=O]2−, and [Ph3BuP] 2 + [Bi2I8 · 2Me2S=O]2−: Syntheses and crystal structures
Sharutin V.V., Egorova I.V., Klepikov N.N., Boyarkina E.A., Sharutina O.K.
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2009
7.
Synthesis and Properties of Hybrid Halobismuthates of N-Acetonylpyridinium Derivatives
Buikin P.A., Rudenko A.Y., Ilyukhin A.B., Kotov V.Y.
Russian Journal of Inorganic Chemistry, 2021
8.
Methylviologen Bromobismuthates
Buikin P.A., Ilyukhin A.B., Laurinavichyute V.K., Kotov V.Y.
Russian Journal of Inorganic Chemistry, 2021
12.
Bismuth(III) Halide Complexes: New Structural Types and New Application Areas
Adonin S.A., Sokolov M.N., Fedin V.P.
Russian Journal of Inorganic Chemistry, 2017
13.
Novel 3D Semiconducting Open-Frameworks based on Cuprous Bromides with Visible Light Driven Photocatalytic Properties
Lei X., Yue C., Wei J., Li R., Mi F., Li Y., Gao L., Liu Q.
Chemistry - A European Journal, 2017
15.
Low-Dimensional Hybrid Cuprous Halides Directed by Transition Metal Complex: Syntheses, Crystal Structures, and Photocatalytic Properties
Lei X., Yue C., Zhao J., Han Y., Yang J., Meng R., Gao C., Ding H., Wang C., Chen W.
Crystal Growth and Design, 2015
19.
Syntheses, crystal structures and photocatalytic properties of four hybrid iodoargentates with zero- and two-dimensional structures
Lei X., Yue C., Feng L., Han Y., Meng R., Yang J., Ding H., Gao C., Wang C.
CrystEngComm, 2016
20.
10.1016/j.mencom.2022.07.028_b0100
Piecha
J. Phys.: Condens. Matter, 2008
21.
Specific heat anomaly in ferroelectric: Bis(imidazolium) pentachloroantimonate(III) (C3 N2 H5)2[SbCl5]
Przesławski J., Piecha-Bisiorek A., Jakubas R.
Journal of Molecular Structure, 2016
22.
Dynamics of Ferroelectric Bis(imidazolium) Pentachloroantimonate(III) by Means of Nuclear Magnetic Resonance 1H Relaxometry and Dielectric Spectroscopy
Piecha-Bisiorek A., Jakubas R., Medycki W., Florek-Wojciechowska M., Wojciechowski M., Kruk D.
Journal of Physical Chemistry A, 2014
23.
10.1016/j.mencom.2022.07.028_b0115
Wojta
J. Phys.: Condens. Matter, 2003
25.
Phase transitions and properties of 0D hybrid iodoantimonate(III) and iodobismuthate(III) semiconducting ferroics: [C(NH2)3]3Bi2I9 and [C(NH2)3]3Sb2I9
Szklarz P., Śmiałkowski M., Bator G., Jakubas R., Cichos J., Karbowiak M., Medycki W., Baran J.
Journal of Molecular Structure, 2021
26.
0D Bismuth(III)-Based Hybrid Ferroelectric: Tris(acetamidinium) Hexabromobismuthate(III)
Mencel K., Kinzhybalo V., Jakubas R., Zaręba J.K., Szklarz P., Durlak P., Drozd M., Piecha-Bisiorek A.
Chemistry of Materials, 2021
28.
Ferroelectricity in Ethylammonium Bismuth-Based Organic–Inorganic Hybrid: (C2H5NH3)2[BiBr5]
Jakubas R., Ga̧gor A., Winiarski M.J., Ptak M., Piecha-Bisiorek A., Ciżman A.
Inorganic Chemistry, 2019
32.
Ultrasensitive Photochromic Iodocuprate(I) Hybrid.
Shen J., Li X., Yu T., Wang F., Hao P., Fu Y.
Inorganic Chemistry, 2016
34.
A terbium chlorobismuthate(III) double salt: Synthesis, structure, and photophysical properties
Ahern J.C., Nicholas A.D., Kelly A.W., Chan B., Pike R.D., Patterson H.H.
Inorganica Chimica Acta, 2018
35.
Alkali metal bismuth(III) chloride double salts
Kelly A.W., Nicholas A., Ahern J.C., Chan B., Patterson H.H., Pike R.D.
Journal of Alloys and Compounds, 2016
36.
Belich N.A., Tychinina A.S., Kuznetsov V.V., Goodilin E.A., Grätzel M., Tarasov A.B.
Mendeleev Communications, 2018
37.
Solution Processing of Methylammonium Lead Iodide Perovskite from γ-Butyrolactone: Crystallization Mediated by Solvation Equilibrium
Fateev S.A., Petrov A.A., Khrustalev V.N., Dorovatovskii P.V., Zubavichus Y.V., Goodilin E.A., Tarasov A.B.
Chemistry of Materials, 2018
38.
Crystallization Features of MAPbI3 Hybrid Perovskite during the Reaction of PbI2 with Reactive Polyiodide Melts
Udalova N.N., Tutantsev A.S., Fateev S.A., Zharenova E.A., Belich N.A., Nemygina E.M., Ryabova A.V., Goodilin E.A., Tarasov A.B.
Russian Journal of Inorganic Chemistry, 2021
39.
A new formation strategy of hybrid perovskites via room temperature reactive polyiodide melts
Petrov A.A., Belich N.A., Grishko A.Y., Stepanov N.M., Dorofeev S.G., Maksimov E.G., Shevelkov A.V., Zakeeruddin S.M., Graetzel M., Tarasov A.B., Goodilin E.A.
Materials Horizons, 2017
40.
Highly Efficient All-Inorganic Planar Heterojunction Perovskite Solar Cells Produced by Thermal Coevaporation of CsI and PbI2
Frolova L.A., Anokhin D.V., Piryazev A.A., Luchkin S.Y., Dremova N.N., Stevenson K.J., Troshin P.A.
Journal of Physical Chemistry Letters, 2016
41.
Grishko A.Y., Zharenova E.A., Goodilin E.A., Tarasov A.B.
Mendeleev Communications, 2021
42.
Marchenko E.I., Fateev S.A., Petrov A.A., Goodilin E.A., Tarasov A.B.
Mendeleev Communications, 2020
44.
Optoelectronic Properties of (CH3NH3)3Sb2I9 Thin Films for Photovoltaic Applications
Hebig J., Kühn I., Flohre J., Kirchartz T.
ACS Energy Letters, 2016
45.
Bismuth Based Hybrid Perovskites A3Bi2I9(A: Methylammonium or Cesium) for Solar Cell Application
Park B., Philippe B., Zhang X., Rensmo H., Boschloo G., Johansson E.M.
Advanced Materials, 2015
47.
From Isolated Anions to Polymer Structures through Linking with I2: Synthesis, Structure, and Properties of Two Complex Bismuth(III) Iodine Iodides
Shestimerova T.A., Yelavik N.A., Mironov A.V., Kuznetsov A.N., Bykov M.A., Grigorieva A.V., Utochnikova V.V., Lepnev L.S., Shevelkov A.V.
Inorganic Chemistry, 2018
49.
Molecular and Supramolecular Structures of Triiodides and Polyiodobismuthates of Phenylenediammonium and Its N,N-dimethyl Derivative
Shestimerova T.A., Golubev N.A., Bykov M.A., Mironov A.V., Fateev S.A., Tarasov A.B., Turkevych I., Wei Z., Dikarev E.V., Shevelkov A.V.
Molecules, 2021
51.
One-Dimensional Diiodine–Iodobismuthate(III) Hybrids Cat3{[Bi2I9](I2)3}: Syntheses, Stability, and Optical Properties
Usoltsev A.N., Korobeynikov N.A., Novikov A.S., Plyusnin P.E., Kolesov B.A., Fedin V.P., Sokolov M.N., Adonin S.A.
Inorganic Chemistry, 2020
52.
van der Waals Volumes and Radii of Metals in Covalent Compounds
Bondi A.
The Journal of Physical Chemistry, 1966
55.
SHELXT– Integrated space-group and crystal-structure determination
Sheldrick G.M.
Acta Crystallographica Section A: Foundations and Advances, 2015
56.
Crystal structure refinement withSHELXL
Sheldrick G.M.
Acta crystallographica. Section C, Structural chemistry, 2015
57.
OLEX2: a complete structure solution, refinement and analysis program
Dolomanov O.V., Bourhis L.J., Gildea R.J., Howard J.A., Puschmann H.
Journal of Applied Crystallography, 2009