Keywords
alcohols
alkanols
cobalt compounds
heterogeneous catalysis
syngas
transition metal sulfide catalysts
Abstract
The influence of textural characteristics on the catalytic performance of supported KCoMoS2 catalysts was explored to provide essential information for the design of better catalysts for the synthesis of higher alcohols (C1–C5) from syngas. Syngas conversion was carried out over KCoMoS2 catalysts supported on various mesoporous (alumina and carbon-coated alumina) and microporous (two types of powdered activated carbons) materials. The experimental results show that catalysts supported over microporous materials exhibit higher catalytic activity in HAS from syngas than catalysts based on mesoporous materials.
References
1.
10.1016/j.mencom.2022.07.026_b0005
Andersson
Appl. Catal., A,
2012
2.
Osman M.E., Maximov V.V., Dorokhov V.S., Mukhin V.M., Sheshko T.F., Kooyman P.J., Kogan V.M.
Catalysts,
2021
3.
Zaman S., Smith K.J.
Catalysis Reviews - Science and Engineering,
2012
4.
Andersson R., Boutonnet M., Järås S.
Fuel,
2013
5.
Dipheko T.D., Eliseev O.L., Agafonov Y.A., Tsapkina M.V., Maximov V.V., Osman M.E., Cherednichenko A.G., Kogan V.M.
Mendeleev Communications,
2021
6.
Permyakov E.A., Dorokhov V.S., Maximov V.V., Nikulshin P.A., Pimerzin A.A., Kogan V.M.
Catalysis Today,
2018
7.
Maximov V.V., Permyakov E.A., Dorokhov V.S., Wang A., Kooyman P.J., Kogan V.M.
ChemCatChem,
2020
8.
Sakata Y., Tamaura Y., Imamura H., Watanabe M.
Studies in Surface Science and Catalysis,
2006
9.
Pérez-Mayoral E., Calvino-Casilda V., Soriano E.
Catalysis Science and Technology,
2016
10.
Anashkin Y.V., Ishutenko D.I., Maximov V.V., Pimerzin A.A., Kogan V.M., Nikulshin P.A.
Reaction Kinetics, Mechanisms and Catalysis,
2019
11.
Surisetty V.R., Tavasoli A., Dalai A.K.
Applied Catalysis A: General,
2009
12.
Surisetty V.R., Dalai A.K., Kozinski J.
Applied Catalysis A: General,
2011
13.
Surisetty V.R., Eswaramoorthi I., Dalai A.K.
Fuel,
2012
14.
Nikulshin P.A., Salnikov V.A., Mozhaev A.V., Minaev P.P., Kogan V.M., Pimerzin A.A.
Journal of Catalysis,
2014
15.
Dorokhov V.S., Kamorin M.A., Rozhdestvenskaya N.N., Kogan V.M.
Comptes Rendus Chimie,
2016
16.
Lv M., Xie W., Sun S., Wu G., Zheng L., Chu S., Gao C., Bao J.
Catalysis Science and Technology,
2015
17.
Liu Y., Murata K., Inaba M.
Reaction Kinetics, Mechanisms and Catalysis,
2014
18.
Yadav G.D., Kamble S.B.
Industrial & Engineering Chemistry Research,
2008
19.
Daage M., Chianelli R.R.
Journal of Catalysis,
1994