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Selective hydrogenation of α,β-unsaturated aldehydes over Pt supported on cerium–zirconium mixed oxide of different composition

, 
Elena Andreevna Redina 1
Elena Andreevna Redina
, 
Gennady Ivanovich Kapustin 1
Gennady Ivanovich Kapustin
, 
Igor Vladimirovich Mishin 1
Igor Vladimirovich Mishin
,  , 
Leonid Modestovich Kustov 1, 2, 3
Leonid Modestovich Kustov
10.1016/j.mencom.2022.07.019
Published 2022-07-01
Communication , Volume 32, Issue 4, 488-491
4
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Vikanova K. V. et al. Selective hydrogenation of α,β-unsaturated aldehydes over Pt supported on cerium–zirconium mixed oxide of different composition // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 488-491.
GOST all authors (up to 50) Copy
Vikanova K. V., Redina E. A., Kapustin G. I., Mishin I. V., Davshan N. A., Kustov L. M. Selective hydrogenation of α,β-unsaturated aldehydes over Pt supported on cerium–zirconium mixed oxide of different composition // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 488-491.
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TY - JOUR
DO - 10.1016/j.mencom.2022.07.019
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.019
TI - Selective hydrogenation of α,β-unsaturated aldehydes over Pt supported on cerium–zirconium mixed oxide of different composition
T2 - Mendeleev Communications
AU - Vikanova, Kseniia Vladimirovna
AU - Redina, Elena Andreevna
AU - Kapustin, Gennady Ivanovich
AU - Mishin, Igor Vladimirovich
AU - Davshan, Nikolay Alekseevich
AU - Kustov, Leonid Modestovich
PY - 2022
DA - 2022/07/01
PB - Mendeleev Communications
SP - 488-491
IS - 4
VL - 32
ER -
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@article{2022_Vikanova,
author = {Kseniia Vladimirovna Vikanova and Elena Andreevna Redina and Gennady Ivanovich Kapustin and Igor Vladimirovich Mishin and Nikolay Alekseevich Davshan and Leonid Modestovich Kustov},
title = {Selective hydrogenation of α,β-unsaturated aldehydes over Pt supported on cerium–zirconium mixed oxide of different composition},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.019},
number = {4},
pages = {488--491},
doi = {10.1016/j.mencom.2022.07.019}
}
MLA
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MLA Copy
Vikanova, Kseniia Vladimirovna, et al. “Selective hydrogenation of α,β-unsaturated aldehydes over Pt supported on cerium–zirconium mixed oxide of different composition.” Mendeleev Communications, vol. 32, no. 4, Jul. 2022, pp. 488-491. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.019.

Keywords

cerium oxide
cinnamaldehyde
cinnamyl alcohol
platinum
selective hydrogenation
unsaturated alcohol synthesis
zirconium oxide
α,b-unsaturated aldehydes

Abstract

Cerium–zirconium mixed oxides with different Ce/Zr ratio were prepared and used as supports for Pt-containing catalysts. The study of the catalysts in the cinnamaldehyde hydrogenation reaction has shown that cinnamaldehyde conversion and cinnamyl alcohol selectivity strongly depend on the CeO2 content in the support. The highest cinnamyl alcohol yield of 81% was obtained in 105 min at room temperature and atmospheric pressure over the 1%Pt/CeO2–ZrO2 catalyst with Ce : Zr atomic ratio equal to 4 : 1.

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