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Cyclopentadienyl rhodium(III) complexes as catalysts for the insertion of phenyldiazoacetate into E−H bonds

Alina Alekseevna Komarova 1
Alina Alekseevna Komarova
, 
Dmitry Victorovich Muratov 1
Dmitry Victorovich Muratov
, 
Dmitrii Sergeevich Perekalin 1, 2
Dmitrii Sergeevich Perekalin
10.1016/j.mencom.2022.07.017
Published 2022-07-01
Communication , Volume 32, Issue 4, 482-484
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Komarova A. A., Muratov D. V., Perekalin D. S. Cyclopentadienyl rhodium(III) complexes as catalysts for the insertion of phenyldiazoacetate into E−H bonds // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 482-484.
GOST all authors (up to 50) Copy
Komarova A. A., Muratov D. V., Perekalin D. S. Cyclopentadienyl rhodium(III) complexes as catalysts for the insertion of phenyldiazoacetate into E−H bonds // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 482-484.
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TY - JOUR
DO - 10.1016/j.mencom.2022.07.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.017
TI - Cyclopentadienyl rhodium(III) complexes as catalysts for the insertion of phenyldiazoacetate into E−H bonds
T2 - Mendeleev Communications
AU - Komarova, Alina Alekseevna
AU - Muratov, Dmitry Victorovich
AU - Perekalin, Dmitrii Sergeevich
PY - 2022
DA - 2022/07/01
PB - Mendeleev Communications
SP - 482-484
IS - 4
VL - 32
ER -
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@article{2022_Komarova,
author = {Alina Alekseevna Komarova and Dmitry Victorovich Muratov and Dmitrii Sergeevich Perekalin},
title = {Cyclopentadienyl rhodium(III) complexes as catalysts for the insertion of phenyldiazoacetate into E−H bonds},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.017},
number = {4},
pages = {482--484},
doi = {10.1016/j.mencom.2022.07.017}
}
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Komarova, Alina Alekseevna, et al. “Cyclopentadienyl rhodium(III) complexes as catalysts for the insertion of phenyldiazoacetate into E−H bonds.” Mendeleev Communications, vol. 32, no. 4, Jul. 2022, pp. 482-484. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.017.

Keywords

catalysis
Cyclopentadienyl ligands
diazo compounds
insertion
rhodium complexes

Abstract

Rhodium(III) complexes catalyze the insertion of carbenoids generated from diazo compounds into E−H bonds (E = B, Si, N, but not C), although less efficiently than classical rhodium(II) carboxylates, despite formally higher oxidation state of the metal.

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