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Copper-containing polymethylsilsesquioxane nanocomposites in catalytic olefination reaction

Alexander Yur'evich Vasil'kov 1
Alexander Yur'evich Vasil'kov
,  , 
Vasilii Mikhailovich Muzalevskiy 3
Vasilii Mikhailovich Muzalevskiy
,  , 
Alexander Yur'evich Pereyaslavtsev 4
Alexander Yur'evich Pereyaslavtsev
,  , 
Valentin Georgievich Nenajdenko 3
Valentin Georgievich Nenajdenko
, 
Aziz Mansurovich Muzafarov 1, 2
Aziz Mansurovich Muzafarov
10.1016/j.mencom.2022.07.016
Published 2022-07-01
Communication , Volume 32, Issue 4, 478-481
8
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Vasil'kov A. Y. et al. Copper-containing polymethylsilsesquioxane nanocomposites in catalytic olefination reaction // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 478-481.
GOST all authors (up to 50) Copy
Vasil'kov A. Y., Migulin D. A., Muzalevskiy V. M., Naumkin A. V., Pereyaslavtsev A. Y., Zubavichus Y. V., Nenajdenko V. G., Muzafarov A. M. Copper-containing polymethylsilsesquioxane nanocomposites in catalytic olefination reaction // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 478-481.
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TY - JOUR
DO - 10.1016/j.mencom.2022.07.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.016
TI - Copper-containing polymethylsilsesquioxane nanocomposites in catalytic olefination reaction
T2 - Mendeleev Communications
AU - Vasil'kov, Alexander Yur'evich
AU - Migulin, Dmitry Alekseevich
AU - Muzalevskiy, Vasilii Mikhailovich
AU - Naumkin, Alexander Vasil'evich
AU - Pereyaslavtsev, Alexander Yur'evich
AU - Zubavichus, Yan Vitautasovich
AU - Nenajdenko, Valentin Georgievich
AU - Muzafarov, Aziz Mansurovich
PY - 2022
DA - 2022/07/01
PB - Mendeleev Communications
SP - 478-481
IS - 4
VL - 32
ER -
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@article{2022_Vasil'kov,
author = {Alexander Yur'evich Vasil'kov and Dmitry Alekseevich Migulin and Vasilii Mikhailovich Muzalevskiy and Alexander Vasil'evich Naumkin and Alexander Yur'evich Pereyaslavtsev and Yan Vitautasovich Zubavichus and Valentin Georgievich Nenajdenko and Aziz Mansurovich Muzafarov},
title = {Copper-containing polymethylsilsesquioxane nanocomposites in catalytic olefination reaction},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.016},
number = {4},
pages = {478--481},
doi = {10.1016/j.mencom.2022.07.016}
}
MLA
Cite this
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Vasil'kov, Alexander Yur'evich, et al. “Copper-containing polymethylsilsesquioxane nanocomposites in catalytic olefination reaction.” Mendeleev Communications, vol. 32, no. 4, Jul. 2022, pp. 478-481. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.016.

Keywords

p-chlorobenz- aldehyde
catalytic olefination
copper nanoparticles
halostyrenes
hydrazones
metal-vapor synthesis
polyhaloalkanes
polymethylsilsesquioxane

Abstract

New copper-containing organosilicon hybrid materials were synthesized by the reaction of branched polymethyl- silsesquioxane with copper nanoparticles prepared by the metal-vapor synthesis. Hybrid materials showed a high activity in the catalytic olefination of p-chlorobenzaldehyde hydrazone with polyhaloalkanes such as CBrCl3, CBr4 and CF CBr to afford the corresponding halostyrenes in the yields above 80%. The structure and composition of the prepared nanocomposites were studied by X-ray using synchrotron radiation to show that the active sites of the catalysts are mixed copper(I)–copper(II) oxides (Cu–Cu2O–CuO) in nature.

References

1.
Polyfluorinated Ethanes as Versatile Fluorinated C2-Building Blocks for Organic Synthesis
Nenajdenko V.G., Muzalevskiy V.M., Shastin A.V.
Chemical Reviews, 2015
2.
A novel reaction of double carbon-carbon bond formation: synthesis of 2,2-dichlorostyrenes
Shastin A.V., Korotchenko V.N., Nenaidenko V.G., Balenkova E.S.
Russian Chemical Bulletin, 1999
3.
A novel method for the synthesis of dichloroalkenes
Nenajdenko V.G., Shastin A.V., Muzalevskii V.M., Balenkova E.S.
Russian Chemical Bulletin, 2004
5.
Freons in catalytic olefination reaction. Synthesis of fluorinated compounds from the products of olefination
Balenkova E.S., Shastin A.V., Muzalevskiy V.M., Nenajdenko V.G.
Russian Journal of Organic Chemistry, 2016
6.
Electrochemical CO2 Reduction Reaction over Cu Nanoparticles with Tunable Activity and Selectivity Mediated by Functional Groups in Polymeric Binder
Chang Q., Lee J.H., Liu Y., Xie Z., Hwang S., Marinkovic N.S., Park A.A., Kattel S., Chen J.G.
JACS Au, 2021
7.
Dynamics of Copper-Containing Porous Organic Framework Catalysts Reveal Catalytic Behavior Controlled by the Polymer Structure
Wu Z., Zhang X., Goodman E.D., Huang W., Riscoe A.R., Yacob S., Cargnello M.
ACS Catalysis, 2020
9.
10.1016/j.mencom.2022.07.016_b0045
Wang
Green Chem., 1949
10.
Single Chain Polymeric Nanoparticles to Promote Selective Hydroxylation Reactions of Phenol Catalyzed by Copper
Thanneeru S., Duay S.S., Jin L., Fu Y., Angeles-Boza A.M., He J.
ACS Macro Letters, 2017
11.
Borisov I.S., Mladentsev D.Y., Guzeev B.A., Goryunov G.P., Uborsky D.V., Vittoria A., Cipullo R., Busico V., Friederichs N., Voskoboynikov A.Z.
Mendeleev Communications, 2020
12.
Chemistry of metallasiloxanes. Current trends and new concepts
Levitsky M.M., Zavin B.G., Bilyachenko A.N.
Russian Chemical Reviews, 2007
13.
Cage-like metallasilsesquioxanes in catalysis: A review
Levitsky M.M., Yalymov A.I., Kulakova A.N., Petrov А.А., Bilyachenko А.N.
Journal of Molecular Catalysis A Chemical, 2017
14.
Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review
Levitsky M.M., Zubavichus Y.V., Korlyukov A.A., Khrustalev V.N., Shubina E.S., Bilyachenko A.N.
Journal of Cluster Science, 2019
15.
Chemical and catalytic activity of copper nanoparticles prepared via metal vapor synthesis
Ponce A.A., Klabunde K.J.
Journal of Molecular Catalysis A Chemical, 2005
16.
Chitosan doped with nanoparticles of copper, nickel and cobalt
Cárdenas-Triviño G., Elgueta C., Vergara L., Ojeda J., Valenzuela A., Cruzat C.
International Journal of Biological Macromolecules, 2017
19.
Low-Temperature Metallic Alloying of Copper and Silver Nanoparticles with Gold Nanoparticles through Digestive Ripening
Smetana A.B., Klabunde K.J., Sorensen C.M., Ponce A.A., Mwale B.
Journal of Physical Chemistry B, 2006
20.
Nanoscale Copper Particles Derived from Solvated Cu Atoms in the Activation of Molecular Oxygen
Vitulli G., Bernini M., Bertozzi S., Pitzalis E., Salvadori P., Coluccia S., Martra G.
Chemistry of Materials, 2002
21.
Nanoscale Cu supported catalysts in the partial oxidation of cyclohexane with molecular oxygen
Evangelisti C., Vitulli G., Schiavi E., Vitulli M., Bertozzi S., Salvadori P., Bertinetti L., Martra G.
Catalysis Letters, 2007
22.
Nenajdenko V.G., Vasil’kov A.Y., Goldberg A.A., Muzalevskiy V.M., Naumkin A.V., Podshibikhin V.L., Shastin A.V., Balenkova E.S.
Mendeleev Communications, 2010
25.
Obrezkova M.A., Saraeva I.I., Ignat'eva G.M., Vasilenko N.G., Muzafarov A.M.
Mendeleev Communications, 2021
26.
Vasil’kov A.Y., Migulin D.A., Naumkin A.V., Belyakova O.A., Zubavichus Y.V., Abramchuk S.S., Maksimov Y.V., Novichikhin S.V., Muzafarov A.M.
Mendeleev Communications, 2016
28.
Synthesis of the first hyperbranched polyorganoethoxysilsesquioxanes and their chemical transformations to functional core-shell nanogel systems
Migulin D., Tatarinova E., Meshkov I., Cherkaev G., Vasilenko N., Buzin M., Muzafarov A.
Polymer International, 2015
30.
Hybrid Au/CuO Nanoparticles: Effect of Structural Features for Selective Benzyl Alcohol Oxidation
Marelli M., Jouve A., Villa A., Psaro R., Balerna A., Prati L., Evangelisti C.
Journal of Physical Chemistry C, 2019
32.
Cu2O by XPS
Vasquez R.P.
Surface Science Spectra, 1998
33.
NIST X-ray Photoelectron Spectroscopy Database, Version 4.1, National Institute of Standards and Technology, Gaithersburg, 2012, http://srdata.nist.gov/xps.
34.
Recommended Auger parameters for 42 elemental solids
Powell C.J.
Journal of Electron Spectroscopy and Related Phenomena, 2012