Home / Publications / Copper(II) and zinc(II) complexes with terpene derivatives of ethylenediamine: unexpected ligand transformations

Copper(II) and zinc(II) complexes with terpene derivatives of ethylenediamine: unexpected ligand transformations

Yana Alexandrovna Gur'eva 1
Yana Alexandrovna Gur'eva
, 
Olga Alexandrovna Zalevskaya 1
Olga Alexandrovna Zalevskaya
, 
Pavel Alexandrovich Slepukhin 2
Pavel Alexandrovich Slepukhin
10.1016/j.mencom.2022.07.014
Published 2022-07-01
Communication , Volume 32, Issue 4, 471-473
0
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Gur'eva Y. A., Zalevskaya O. A., Slepukhin P. A. Copper(II) and zinc(II) complexes with terpene derivatives of ethylenediamine: unexpected ligand transformations // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 471-473.
GOST all authors (up to 50) Copy
Gur'eva Y. A., Zalevskaya O. A., Slepukhin P. A. Copper(II) and zinc(II) complexes with terpene derivatives of ethylenediamine: unexpected ligand transformations // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 471-473.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2022.07.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.014
TI - Copper(II) and zinc(II) complexes with terpene derivatives of ethylenediamine: unexpected ligand transformations
T2 - Mendeleev Communications
AU - Gur'eva, Yana Alexandrovna
AU - Zalevskaya, Olga Alexandrovna
AU - Slepukhin, Pavel Alexandrovich
PY - 2022
DA - 2022/07/01
PB - Mendeleev Communications
SP - 471-473
IS - 4
VL - 32
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2022_Gur'eva,
author = {Yana Alexandrovna Gur'eva and Olga Alexandrovna Zalevskaya and Pavel Alexandrovich Slepukhin},
title = {Copper(II) and zinc(II) complexes with terpene derivatives of ethylenediamine: unexpected ligand transformations},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.014},
number = {4},
pages = {471--473},
doi = {10.1016/j.mencom.2022.07.014}
}
MLA
Cite this
MLA Copy
Gur'eva, Yana Alexandrovna, et al. “Copper(II) and zinc(II) complexes with terpene derivatives of ethylenediamine: unexpected ligand transformations.” Mendeleev Communications, vol. 32, no. 4, Jul. 2022, pp. 471-473. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.014.

Keywords

copper complexes
crystallization
ethylenediamine
imines
ligands
terpenes
X-ray diffraction analysis
zinc complexes

Abstract

Crystallization of copper and zinc complexes with imino terpene derivatives of ethylenediamine causes unexpected chemical transformation of the ligand. Copper(II) chloride catalyzes the hydrolysis of the imine and also acts as a halogenating agent. Crystallization of the zinc complex in acetone is accompanied by the condensation of the ketone with the primary amino group of the ligand.

References

2.
Zinc Complexes with Nitrogen Donor Ligands as Anticancer Agents
Porchia M., Pellei M., Del Bello F., Santini C.
Molecules, 2020
4.
Recent Studies on the Antimicrobial Activity of Copper Complexes
Zalevskaya O.A., Gur’eva Y.A.
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2021
5.
Synthesis of New Chiral Palladium Complexes with Multidentate Camphor Schiff Bases
Gur’eva Y.A., Zalevskaya O.A., Alekseev I.A., Slepukhin P.A., Kutchin A.V.
Russian Journal of Organic Chemistry, 2018
6.
Synthesis of new bidentate ligands—terpene derivatives of ethylenediamine and their palladium complexes
Gur’eva Y.A., Alekseev I.N., Zalevskaya O.A., Slepukhin P.A., Kutchin A.V.
Russian Journal of Organic Chemistry, 2016
7.
Palladium complexes with terpene derivatives of ethylenediamine and benzylamine: Synthesis and study of antitumor properties
Zalevskaya O.A., Gur'eva Y.A., Kutchin A.V., Aleksandrova Y.R., Yandulova E.Y., Nikolaeva N.S., Neganova M.E.
Inorganica Chimica Acta, 2021
12.
Highly Regioselective α-Chlorination of the BODIPY Chromophore with Copper(II) Chloride
Zhou X., Yu C., Feng Z., Yu Y., Wang J., Hao E., Wei Y., Mu X., Jiao L.
Organic Letters, 2015
13.
Discovery of a new class of antiviral compounds: Camphor imine derivatives
Sokolova A.S., Yarovaya O.I., Shernyukov A.V., Gatilov Y.V., Razumova Y.V., Zarubaev V.V., Tretiak T.S., Pokrovsky A.G., Kiselev O.I., Salakhutdinov N.F.
European Journal of Medicinal Chemistry, 2015