Home / Publications / Cascade transformation of 4-hydroxymethyl-2-carene into novel cage methanopyrano[4,3-b]thieno[3,2-g]benzofuran derivative

Cascade transformation of 4-hydroxymethyl-2-carene into novel cage methanopyrano[4,3-b]thieno[3,2-g]benzofuran derivative

Nikolai Sergeevich Li-Zhulanov 1
Nikolai Sergeevich Li-Zhulanov
Irina Valer'evna Il'ina 1
Irina Valer'evna Il'ina
Alexander Yu Sidorenko 2
Alexander Yu Sidorenko
Dina Vladimirovna Korchagina 1
Dina Vladimirovna Korchagina
Konstantin Petrovich Volcho 1
Konstantin Petrovich Volcho
Vladimir Enokovich Agabekov 2
Vladimir Enokovich Agabekov
Nariman Faridovich Salakhutdinov 1
Nariman Faridovich Salakhutdinov
Published 2022-07-01
CommunicationVolume 32, Issue 4, 443-445
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Li-Zhulanov N. S. et al. Cascade transformation of 4-hydroxymethyl-2-carene into novel cage methanopyrano[4,3-b]thieno[3,2-g]benzofuran derivative // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 443-445.
GOST all authors (up to 50) Copy
Li-Zhulanov N. S., Il'ina I. V., Sidorenko A. Yu., Korchagina D. V., Volcho K. P., Agabekov V. E., Salakhutdinov N. F. Cascade transformation of 4-hydroxymethyl-2-carene into novel cage methanopyrano[4,3-b]thieno[3,2-g]benzofuran derivative // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 443-445.
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TY - JOUR
DO - 10.1016/j.mencom.2022.07.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.005
TI - Cascade transformation of 4-hydroxymethyl-2-carene into novel cage methanopyrano[4,3-b]thieno[3,2-g]benzofuran derivative
T2 - Mendeleev Communications
AU - Li-Zhulanov, Nikolai Sergeevich
AU - Il'ina, Irina Valer'evna
AU - Sidorenko, Alexander Yu
AU - Korchagina, Dina Vladimirovna
AU - Volcho, Konstantin Petrovich
AU - Agabekov, Vladimir Enokovich
AU - Salakhutdinov, Nariman Faridovich
PY - 2022
DA - 2022/07/01
PB - Mendeleev Communications
SP - 443-445
IS - 4
VL - 32
ER -
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@article{2022_Li-Zhulanov,
author = {Nikolai Sergeevich Li-Zhulanov and Irina Valer'evna Il'ina and Alexander Yu Sidorenko and Dina Vladimirovna Korchagina and Konstantin Petrovich Volcho and Vladimir Enokovich Agabekov and Nariman Faridovich Salakhutdinov},
title = {Cascade transformation of 4-hydroxymethyl-2-carene into novel cage methanopyrano[4,3-b]thieno[3,2-g]benzofuran derivative},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.005},
number = {4},
pages = {443--445},
doi = {10.1016/j.mencom.2022.07.005}
}
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Li-Zhulanov, Nikolai Sergeevich, et al. “Cascade transformation of 4-hydroxymethyl-2-carene into novel cage methanopyrano[4,3-b]thieno[3,2-g]benzofuran derivative.” Mendeleev Communications, vol. 32, no. 4, Jul. 2022, pp. 443-445. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.07.005.

Keywords

carene
clays
halloysite
heterogeneous catalysis
montmorillonite K10
pyrano[4,3-b]thieno[3,2-g]benzofuran
terpenoids
thiophene-2-carbaldehyde

Abstract

Reaction of trans-4-hydroxymethyl-2-carene with thiophene- 2-carbaldehyde under heterogeneous catalysis by K10 clay affordsubstitutedmethanopyrano[4,3-b]thieno[3,2-g]- benzofuran, a complex 5-membered chiral cage heterocyclic compound containing two thiophene moieties. Its structure was determined by 1D and 2D NMR experiments (HSQC, HMBC, COSY, NOESY) and HRMS.

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