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The features of ignition of hydrogen–methane and hydrogen–isobutene mixtures with oxygen over Rh and Pd at low pressures

Nikolai Mihailovich Rubtsov 1
Nikolai Mihailovich Rubtsov
, 
Victor Iosifovich Chernysh 1
Victor Iosifovich Chernysh
, 
Georgii Igorevich Tsvetkov 1
Georgii Igorevich Tsvetkov
,  , 
Igor Olegovich Shamshin 2
Igor Olegovich Shamshin
10.1016/j.mencom.2022.05.039
Published 2022-04-29
Communication , Volume 32, Issue 3, 405-407
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Rubtsov N. M. et al. The features of ignition of hydrogen–methane and hydrogen–isobutene mixtures with oxygen over Rh and Pd at low pressures // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 405-407.
GOST all authors (up to 50) Copy
Rubtsov N. M., Chernysh V. I., Tsvetkov G. I., Troshin K. Y., Shamshin I. O. The features of ignition of hydrogen–methane and hydrogen–isobutene mixtures with oxygen over Rh and Pd at low pressures // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 405-407.
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TY - JOUR
DO - 10.1016/j.mencom.2022.05.039
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.039
TI - The features of ignition of hydrogen–methane and hydrogen–isobutene mixtures with oxygen over Rh and Pd at low pressures
T2 - Mendeleev Communications
AU - Rubtsov, Nikolai Mihailovich
AU - Chernysh, Victor Iosifovich
AU - Tsvetkov, Georgii Igorevich
AU - Troshin, Kirill Yakovlevich
AU - Shamshin, Igor Olegovich
PY - 2022
DA - 2022/04/29
PB - Mendeleev Communications
SP - 405-407
IS - 3
VL - 32
ER -
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@article{2022_Rubtsov,
author = {Nikolai Mihailovich Rubtsov and Victor Iosifovich Chernysh and Georgii Igorevich Tsvetkov and Kirill Yakovlevich Troshin and Igor Olegovich Shamshin},
title = {The features of ignition of hydrogen–methane and hydrogen–isobutene mixtures with oxygen over Rh and Pd at low pressures},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.039},
number = {3},
pages = {405--407},
doi = {10.1016/j.mencom.2022.05.039}
}
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Rubtsov, Nikolai Mihailovich, et al. “The features of ignition of hydrogen–methane and hydrogen–isobutene mixtures with oxygen over Rh and Pd at low pressures.” Mendeleev Communications, vol. 32, no. 3, Apr. 2022, pp. 405-407. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.039.

Keywords

carbon nanotubes
hydrogen
ignition
isobutene
methane
oxidation
palladium
rhodium

Abstract

The flammability limits of stoichiometric mixtures (20–80% H2 + 80–20% CH4) + O2 over Rh and Pd were determined in the pressure range 0–200 Torr and the temperature range 200–500 °C. It has been shown that the dark reaction in the mixture (80% H2 + 20% C4H8)stoich + O2 leads to the formation of carbon nanotubes with a mean diameter of 10–100 nm.

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