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A simple rhodium-catalyzed addition reaction of aldehydes with arylboronic acids in aqueous γ-valerolactone

Min-xiao Xu 1
Min-xiao Xu
, 
Kai-Ming Zhang 1, 2
Kai-Ming Zhang
, 
Jie Zhang 3
Jie Zhang
1 Jiangsu Police Institute, Nanjing, P.R. China
3 College of Pharmaceutics, Jinhua Polytechnic, Jinhua, P.R. China
10.1016/j.mencom.2022.05.036
Published 2022-04-29
Communication , Volume 32, Issue 3, 397-398
3
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Xu M., Zhang K., Zhang J. A simple rhodium-catalyzed addition reaction of aldehydes with arylboronic acids in aqueous γ-valerolactone // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 397-398.
GOST all authors (up to 50) Copy
Xu M., Zhang K., Zhang J. A simple rhodium-catalyzed addition reaction of aldehydes with arylboronic acids in aqueous γ-valerolactone // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 397-398.
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TY - JOUR
DO - 10.1016/j.mencom.2022.05.036
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.036
TI - A simple rhodium-catalyzed addition reaction of aldehydes with arylboronic acids in aqueous γ-valerolactone
T2 - Mendeleev Communications
AU - Xu, Min-xiao
AU - Zhang, Kai-Ming
AU - Zhang, Jie
PY - 2022
DA - 2022/04/29
PB - Mendeleev Communications
SP - 397-398
IS - 3
VL - 32
ER -
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@article{2022_Xu,
author = {Min-xiao Xu and Kai-Ming Zhang and Jie Zhang},
title = {A simple rhodium-catalyzed addition reaction of aldehydes with arylboronic acids in aqueous γ-valerolactone},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.036},
number = {3},
pages = {397--398},
doi = {10.1016/j.mencom.2022.05.036}
}
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MLA Copy
Xu, Min-xiao, et al. “A simple rhodium-catalyzed addition reaction of aldehydes with arylboronic acids in aqueous γ-valerolactone.” Mendeleev Communications, vol. 32, no. 3, Apr. 2022, pp. 397-398. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.036.

Keywords

addition reaction
aldehydes
arylboronic acids
benzylic alcohols
green solvent
Rhodium catalysis
γ-valerolactone

Abstract

A simple rhodium-catalyzed addition reaction of aldehydes with arylboronic acids in aqueous γ-valerolactone provides the corresponding benzylic alcohols in moderate to good yields. Other organoboron reagents (boronic esters, aryl-trifluoroborates, etc.) also showed good compatibilities, albeit with relatively lower yields.

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