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One-pot assembling of selenazolines from elemental selenium, alkenes and acetonitrile

Evgeny Olegovich Kurkutov 1
Evgeny Olegovich Kurkutov
, 
Bagrat Armenovich Shainyan 1
Bagrat Armenovich Shainyan
10.1016/j.mencom.2022.05.035
Published 2022-04-29
Communication , Volume 32, Issue 3, 395-396
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Kurkutov E. O., Shainyan B. A. One-pot assembling of selenazolines from elemental selenium, alkenes and acetonitrile // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 395-396.
GOST all authors (up to 50) Copy
Kurkutov E. O., Shainyan B. A. One-pot assembling of selenazolines from elemental selenium, alkenes and acetonitrile // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 395-396.
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TY - JOUR
DO - 10.1016/j.mencom.2022.05.035
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.035
TI - One-pot assembling of selenazolines from elemental selenium, alkenes and acetonitrile
T2 - Mendeleev Communications
AU - Kurkutov, Evgeny Olegovich
AU - Shainyan, Bagrat Armenovich
PY - 2022
DA - 2022/04/29
PB - Mendeleev Communications
SP - 395-396
IS - 3
VL - 32
ER -
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@article{2022_Kurkutov,
author = {Evgeny Olegovich Kurkutov and Bagrat Armenovich Shainyan},
title = {One-pot assembling of selenazolines from elemental selenium, alkenes and acetonitrile},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.035},
number = {3},
pages = {395--396},
doi = {10.1016/j.mencom.2022.05.035}
}
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Kurkutov, Evgeny Olegovich, and Bagrat Armenovich Shainyan. “One-pot assembling of selenazolines from elemental selenium, alkenes and acetonitrile.” Mendeleev Communications, vol. 32, no. 3, Apr. 2022, pp. 395-396. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.035.

Keywords

1,3-selenazolines
acetonitrile
alkenes
iodine assistance
organoselenium compounds
selenium
solvent interception

Abstract

A new method for assembling 1,3-selenazolines by the iodine- mediated reaction of the simplest building blocks such as elemental selenium, alkenes and acetonitrile has been discovered. A proposed mechanism includes the addition of the intermediate selenium iodides to alkene with subsequent solvent interception by the formed seleniranium ion.

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