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Diene-transmissive hetero-Diels–Alder reaction of distyryl thioketone

Ekaterina Andreevna Merkulova 1
Ekaterina Andreevna Merkulova
, 
Alexei Vladislavovich Kolobov 1
Alexei Vladislavovich Kolobov
, 
Konstantin Alexandrovich Lyssenko 2
Konstantin Alexandrovich Lyssenko
, 
Valentin Georgievich Nenajdenko 2
Valentin Georgievich Nenajdenko
10.1016/j.mencom.2022.05.031
Published 2022-04-29
Communication , Volume 32, Issue 3, 384-385
7
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Merkulova E. A. et al. Diene-transmissive hetero-Diels–Alder reaction of distyryl thioketone // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 384-385.
GOST all authors (up to 50) Copy
Merkulova E. A., Kolobov A. V., Lyssenko K. A., Nenajdenko V. G. Diene-transmissive hetero-Diels–Alder reaction of distyryl thioketone // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 384-385.
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TY - JOUR
DO - 10.1016/j.mencom.2022.05.031
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.031
TI - Diene-transmissive hetero-Diels–Alder reaction of distyryl thioketone
T2 - Mendeleev Communications
AU - Merkulova, Ekaterina Andreevna
AU - Kolobov, Alexei Vladislavovich
AU - Lyssenko, Konstantin Alexandrovich
AU - Nenajdenko, Valentin Georgievich
PY - 2022
DA - 2022/04/29
PB - Mendeleev Communications
SP - 384-385
IS - 3
VL - 32
ER -
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@article{2022_Merkulova,
author = {Ekaterina Andreevna Merkulova and Alexei Vladislavovich Kolobov and Konstantin Alexandrovich Lyssenko and Valentin Georgievich Nenajdenko},
title = {Diene-transmissive hetero-Diels–Alder reaction of distyryl thioketone},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.031},
number = {3},
pages = {384--385},
doi = {10.1016/j.mencom.2022.05.031}
}
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Merkulova, Ekaterina Andreevna, et al. “Diene-transmissive hetero-Diels–Alder reaction of distyryl thioketone.” Mendeleev Communications, vol. 32, no. 3, Apr. 2022, pp. 384-385. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.031.

Keywords

3,4-dihydro-2H-thiopyrans
diene-transmissive reactions
dienes
dienophiles
enethiones
hetero-Diels–Alder reaction
Lawesson’s reagent
thioketones

Abstract

The reaction distyryl thioketone with donor alkenes (norbornene and styrene) gives adducts of the hetero-Diels–Alder reaction. In the case of maleic acid derivatives, a tandem reaction occurs which leads to polycyclic derivatives of 3,4-dihydro-2H-thiopyran. The stereochemical features of the ongoing transformations were examined.

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