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Novel chromeno[2,3-c]pyrroles synthesized via intramolecular rhodium(ii) carbene trapping

Evgeny Gennadievich Chupakhin 1, 2
Evgeny Gennadievich Chupakhin
, 
Grigoriy Pavlovich Kantin 2
Grigoriy Pavlovich Kantin
, 
Dmitry Viktorovich Dar’in 2
Dmitry Viktorovich Dar’in
, 
Mikhail Yur'evich Krasavin 1, 2
Mikhail Yur'evich Krasavin
10.1016/j.mencom.2022.05.030
Published 2022-04-29
Communication , Volume 32, Issue 3, 382-383
3
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Chupakhin E. G. et al. Novel chromeno[2,3-c]pyrroles synthesized via intramolecular rhodium(ii) carbene trapping // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 382-383.
GOST all authors (up to 50) Copy
Chupakhin E. G., Kantin G. P., Dar’in D. V., Krasavin M. Y. Novel chromeno[2,3-c]pyrroles synthesized via intramolecular rhodium(ii) carbene trapping // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 382-383.
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TY - JOUR
DO - 10.1016/j.mencom.2022.05.030
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.030
TI - Novel chromeno[2,3-c]pyrroles synthesized via intramolecular rhodium(ii) carbene trapping
T2 - Mendeleev Communications
AU - Chupakhin, Evgeny Gennadievich
AU - Kantin, Grigoriy Pavlovich
AU - Dar’in, Dmitry Viktorovich
AU - Krasavin, Mikhail Yur'evich
PY - 2022
DA - 2022/04/29
PB - Mendeleev Communications
SP - 382-383
IS - 3
VL - 32
ER -
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@article{2022_Chupakhin,
author = {Evgeny Gennadievich Chupakhin and Grigoriy Pavlovich Kantin and Dmitry Viktorovich Dar’in and Mikhail Yur'evich Krasavin},
title = {Novel chromeno[2,3-c]pyrroles synthesized via intramolecular rhodium(ii) carbene trapping},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.030},
number = {3},
pages = {382--383},
doi = {10.1016/j.mencom.2022.05.030}
}
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Chupakhin, Evgeny Gennadievich, et al. “Novel chromeno[2,3-c]pyrroles synthesized via intramolecular rhodium(ii) carbene trapping.” Mendeleev Communications, vol. 32, no. 3, Apr. 2022, pp. 382-383. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.030.

Keywords

2H-chromenes
5-diones
chromeno[2,3-c]pyrroles
intramolecular O-H insertion
pyrrolidine-2
rhodium(u) complexes
α-diazo carbonyl compounds

Abstract

Rhodium(ii) carbenes generated from (E)-3-diazo-4-(2-hydroxybenzylidene)-1-phenylpyrrolidine-2,5-dione under- went a facile transformation into novel succinimide-fused 2H-chromenes, chromeno[2,3-c]pyrrole-1,3(2H,3aH)-diones. The process presumably involves an intramolecular O-H insertion reaction.

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