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Synthesis and structure of tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane

Nina Olegovna Yarosh 1
Nina Olegovna Yarosh
, 
Larisa Vladimirovna Zhilitskaya 1
Larisa Vladimirovna Zhilitskaya
, 
Irina Vladimirovna Sterkhova 1
Irina Vladimirovna Sterkhova
, 
Mikhail E Plyaskin 2, 3
Mikhail E Plyaskin
, 
Bagrat Armenovich Shainyan 1
Bagrat Armenovich Shainyan
10.1016/j.mencom.2022.05.029
Published 2022-04-29
Communication , Volume 32, Issue 3, 379-381
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Yarosh N. O. et al. Synthesis and structure of tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 379-381.
GOST all authors (up to 50) Copy
Yarosh N. O., Zhilitskaya L. V., Sterkhova I. V., Plyaskin M. E., Shainyan B. A. Synthesis and structure of tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 379-381.
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TY - JOUR
DO - 10.1016/j.mencom.2022.05.029
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.029
TI - Synthesis and structure of tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane
T2 - Mendeleev Communications
AU - Yarosh, Nina Olegovna
AU - Zhilitskaya, Larisa Vladimirovna
AU - Sterkhova, Irina Vladimirovna
AU - Plyaskin, Mikhail E
AU - Shainyan, Bagrat Armenovich
PY - 2022
DA - 2022/04/29
PB - Mendeleev Communications
SP - 379-381
IS - 3
VL - 32
ER -
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@article{2022_Yarosh,
author = {Nina Olegovna Yarosh and Larisa Vladimirovna Zhilitskaya and Irina Vladimirovna Sterkhova and Mikhail E Plyaskin and Bagrat Armenovich Shainyan},
title = {Synthesis and structure of tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.029},
number = {3},
pages = {379--381},
doi = {10.1016/j.mencom.2022.05.029}
}
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Yarosh, Nina Olegovna, et al. “Synthesis and structure of tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane.” Mendeleev Communications, vol. 32, no. 3, Apr. 2022, pp. 379-381. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.029.

Keywords

alkynes
organogermanium compounds
organosilicon compounds
quantum chemical calculations
X-ray analysis

Abstract

Tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane were synthesized by the reaction of BrMgC≡CSi(CH2Cl)Me2 with SiCl4/GeCl4. Their structures were proved by IR, NMR spectroscopy and X-ray analysis, and compared to the results of MP2/6-311G(d,p) calculations.

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