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Mechanism of hydride abstraction in the electrocyclic phototransformation of heterostilbene

Alina Èduardovna Saifutiarova 1, 2
Alina Èduardovna Saifutiarova
, 
Yurii Viktorovich Fedorov 1
Yurii Viktorovich Fedorov
, 
Elena E Gulakova 1
Elena E Gulakova
, 
Olga Anatol'evna Fedorova 1, 2
Olga Anatol'evna Fedorova
10.1016/j.mencom.2022.05.027
Published 2022-04-29
Communication , Volume 32, Issue 3, 374-376
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Saifutiarova A. È. et al. Mechanism of hydride abstraction in the electrocyclic phototransformation of heterostilbene // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 374-376.
GOST all authors (up to 50) Copy
Saifutiarova A. È., Fedorov Y. V., Gulakova E. E., Fedorova O. A. Mechanism of hydride abstraction in the electrocyclic phototransformation of heterostilbene // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 374-376.
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TY - JOUR
DO - 10.1016/j.mencom.2022.05.027
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.027
TI - Mechanism of hydride abstraction in the electrocyclic phototransformation of heterostilbene
T2 - Mendeleev Communications
AU - Saifutiarova, Alina Èduardovna
AU - Fedorov, Yurii Viktorovich
AU - Gulakova, Elena E
AU - Fedorova, Olga Anatol'evna
PY - 2022
DA - 2022/04/29
PB - Mendeleev Communications
SP - 374-376
IS - 3
VL - 32
ER -
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@article{2022_Saifutiarova,
author = {Alina Èduardovna Saifutiarova and Yurii Viktorovich Fedorov and Elena E Gulakova and Olga Anatol'evna Fedorova},
title = {Mechanism of hydride abstraction in the electrocyclic phototransformation of heterostilbene},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.027},
number = {3},
pages = {374--376},
doi = {10.1016/j.mencom.2022.05.027}
}
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Saifutiarova, Alina Èduardovna, et al. “Mechanism of hydride abstraction in the electrocyclic phototransformation of heterostilbene.” Mendeleev Communications, vol. 32, no. 3, Apr. 2022, pp. 374-376. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.027.

Keywords

E–Z-photoisomerization
electrocyclization
heterostilbenes
hydride abstraction
regiospecific C–N photocyclization

Abstract

A new mechanism of hydride abstraction in the course of a photochemical electrocyclic reaction of heterostilbene in aqueous solution is reported. The study of electrocyclic transformations of heterostilbenes containing different types of heterocyclic residues revealed that the herein estimated mechanism of hydride abstraction is common for heterostilbene photochemical electrocyclization through the formation of new C–N bond.

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