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Optical and electrochemical properties of novel fused tricyclic thiophene–15-crown-5 systems and their complexes with Mg and Ba ions

Sergey Dmitrievich Tokarev 1
Sergey Dmitrievich Tokarev
, 
Anatoly Botezatu 1, 2
Anatoly Botezatu
, 
Andrey Vasil'evich Khoroshutin 2
Andrey Vasil'evich Khoroshutin
, 
Yurii Viktorovich Fedorov 1
Yurii Viktorovich Fedorov
, 
Olga Anatol'evna Fedorova 1
Olga Anatol'evna Fedorova
10.1016/j.mencom.2022.05.025
Published 2022-04-29
Communication , Volume 32, Issue 3, 367-370
5
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Tokarev S. D. et al. Optical and electrochemical properties of novel fused tricyclic thiophene–15-crown-5 systems and their complexes with Mg and Ba ions // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 367-370.
GOST all authors (up to 50) Copy
Tokarev S. D., Botezatu A., Khoroshutin A. V., Fedorov Y. V., Fedorova O. A. Optical and electrochemical properties of novel fused tricyclic thiophene–15-crown-5 systems and their complexes with Mg and Ba ions // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 367-370.
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TY - JOUR
DO - 10.1016/j.mencom.2022.05.025
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.025
TI - Optical and electrochemical properties of novel fused tricyclic thiophene–15-crown-5 systems and their complexes with Mg and Ba ions
T2 - Mendeleev Communications
AU - Tokarev, Sergey Dmitrievich
AU - Botezatu, Anatoly
AU - Khoroshutin, Andrey Vasil'evich
AU - Fedorov, Yurii Viktorovich
AU - Fedorova, Olga Anatol'evna
PY - 2022
DA - 2022/04/29
PB - Mendeleev Communications
SP - 367-370
IS - 3
VL - 32
ER -
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@article{2022_Tokarev,
author = {Sergey Dmitrievich Tokarev and Anatoly Botezatu and Andrey Vasil'evich Khoroshutin and Yurii Viktorovich Fedorov and Olga Anatol'evna Fedorova},
title = {Optical and electrochemical properties of novel fused tricyclic thiophene–15-crown-5 systems and their complexes with Mg and Ba ions},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.025},
number = {3},
pages = {367--370},
doi = {10.1016/j.mencom.2022.05.025}
}
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Tokarev, Sergey Dmitrievich, et al. “Optical and electrochemical properties of novel fused tricyclic thiophene–15-crown-5 systems and their complexes with Mg and Ba ions.” Mendeleev Communications, vol. 32, no. 3, Apr. 2022, pp. 367-370. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.025.

Keywords

absorption
barium complexes
complex formation
crown ethers
fluorescence
magnesium complexes
naphthothiophenes
redox properties
spectroelectrochemistry

Abstract

New polycyclic aromatic derivatives annulated both with thiophene and with 15-crown-5 ether moieties, crown naphthothiophenes, were synthesized via the Mallory photocyclization with the use of iodine as the mild oxidizer, while two isomeric products were readily separated by column chromatography. Their complexation with Ba2+ and Mg2+ cations was examined by both optical and electrochemical methods. Spectroelectrochemical studies indicate that the obtained compounds, depending on their structure, can be chemically stable in the oxidized state

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