Keywords
aluminum complexes
biodegradable polymers
biometals
esterification
PBAT
phenates
polycondensation
polyesters
Abstract
A comparative study of catalytic activity of aryloxy complexes of Mg, Zn and Al in the synthesis of poly(butylene adipate terephthalate) demonstrated the preference of Al-based catalyst containing two bulky substituents in ortho-position of phenol ligand in terms of higher values of PBAT MW and lower yields of cyclic diester side product.
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