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Nitration of benzyl derivatives of acetylated hexaazaisowurtzitane

Darya Aleksandrovna Kulagina 1
Darya Aleksandrovna Kulagina
, 
Artem Sergeyevich Goryaev 1
Artem Sergeyevich Goryaev
, 
Ivan N Chernyshov 1
Ivan N Chernyshov
, 
Sergey Viktorovich Sysolyatin 1
Sergey Viktorovich Sysolyatin
1 Institute for Problems of Chemical & Energetic Technologies, Siberian Branch of the Russian Academy of Sciences, Biysk, Russian Federation
10.1016/j.mencom.2022.05.019
Published 2022-04-29
Communication , Volume 32, Issue 3, 349-350
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Kulagina D. A. et al. Nitration of benzyl derivatives of acetylated hexaazaisowurtzitane // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 349-350.
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Kulagina D. A., Goryaev A. S., Chernyshov I. N., Sysolyatin S. V. Nitration of benzyl derivatives of acetylated hexaazaisowurtzitane // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 349-350.
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TY - JOUR
DO - 10.1016/j.mencom.2022.05.019
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.019
TI - Nitration of benzyl derivatives of acetylated hexaazaisowurtzitane
T2 - Mendeleev Communications
AU - Kulagina, Darya Aleksandrovna
AU - Goryaev, Artem Sergeyevich
AU - Chernyshov, Ivan N
AU - Sysolyatin, Sergey Viktorovich
PY - 2022
DA - 2022/04/29
PB - Mendeleev Communications
SP - 349-350
IS - 3
VL - 32
ER -
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@article{2022_Kulagina,
author = {Darya Aleksandrovna Kulagina and Artem Sergeyevich Goryaev and Ivan N Chernyshov and Sergey Viktorovich Sysolyatin},
title = {Nitration of benzyl derivatives of acetylated hexaazaisowurtzitane},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.019},
number = {3},
pages = {349--350},
doi = {10.1016/j.mencom.2022.05.019}
}
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Kulagina, Darya Aleksandrovna, et al. “Nitration of benzyl derivatives of acetylated hexaazaisowurtzitane.” Mendeleev Communications, vol. 32, no. 3, Apr. 2022, pp. 349-350. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.019.

Keywords

benzyl groups
cage compounds
hexaazaisowurtzitanes
nitrating mixtures
nitration
selective reaction

Abstract

Nitration of N-benzylated 2,4,6,8,10,12-hexaazaisowurtzitane derivatives occurs selectively at para-positions of the benzyl groups. The best reagent for this reaction is ammonium nitrate in sulfuric acid.

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