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Effect of pH on the reaction outcome between tetraacetyl hexaazaisowurtzitane and aldehydes

Darya Aleksandrovna Kulagina 1
Darya Aleksandrovna Kulagina
, 
Sergey Viktorovich Sysolyatin 1
Sergey Viktorovich Sysolyatin
1 Institute for Problems of Chemical & Energetic Technologies, Siberian Branch of the Russian Academy of Sciences, Biysk, Russian Federation
10.1016/j.mencom.2022.05.018
Published 2022-04-29
Communication , Volume 32, Issue 3, 347-348
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Kulagina D. A., Sysolyatin S. V. Effect of pH on the reaction outcome between tetraacetyl hexaazaisowurtzitane and aldehydes // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 347-348.
GOST all authors (up to 50) Copy
Kulagina D. A., Sysolyatin S. V. Effect of pH on the reaction outcome between tetraacetyl hexaazaisowurtzitane and aldehydes // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 347-348.
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TY - JOUR
DO - 10.1016/j.mencom.2022.05.018
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.018
TI - Effect of pH on the reaction outcome between tetraacetyl hexaazaisowurtzitane and aldehydes
T2 - Mendeleev Communications
AU - Kulagina, Darya Aleksandrovna
AU - Sysolyatin, Sergey Viktorovich
PY - 2022
DA - 2022/04/29
PB - Mendeleev Communications
SP - 347-348
IS - 3
VL - 32
ER -
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@article{2022_Kulagina,
author = {Darya Aleksandrovna Kulagina and Sergey Viktorovich Sysolyatin},
title = {Effect of pH on the reaction outcome between tetraacetyl hexaazaisowurtzitane and aldehydes},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.018},
number = {3},
pages = {347--348},
doi = {10.1016/j.mencom.2022.05.018}
}
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Kulagina, Darya Aleksandrovna, and Sergey Viktorovich Sysolyatin. “Effect of pH on the reaction outcome between tetraacetyl hexaazaisowurtzitane and aldehydes.” Mendeleev Communications, vol. 32, no. 3, Apr. 2022, pp. 347-348. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.018.

Keywords

N-aminomethylation
acetals
aldehydes
aminals
cage compounds
formaldehyde
hexaazaisowurtzitanes

Abstract

2,6,8,12-Tetraacetyl-2,4,6,8,10,12-hexaazaisowurtzitane was subjected to N-aminomethylation under various conditions, which afforded new derivatives of aminal nature. The highest yields were achieved when the reactions were carried out in a weak-alkali medium.

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