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Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction

Ludmila Alekseevna Bulygina 1
Ludmila Alekseevna Bulygina
, 
Natalya Sergeevna Khrushcheva 1
Natalya Sergeevna Khrushcheva
, 
Konstantin Alexandrovich Lyssenko 2, 3
Konstantin Alexandrovich Lyssenko
, 
Aleksandr Sergeevich Peregudov 1
Aleksandr Sergeevich Peregudov
10.1016/j.mencom.2022.05.012
Published 2022-04-29
Communication , Volume 32, Issue 3, 331-333
6
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Bulygina L. A. et al. Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 331-333.
GOST all authors (up to 50) Copy
Bulygina L. A., Khrushcheva N. S., Lyssenko K. A., Peregudov A. S. Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 331-333.
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TY - JOUR
DO - 10.1016/j.mencom.2022.05.012
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.012
TI - Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction
T2 - Mendeleev Communications
AU - Bulygina, Ludmila Alekseevna
AU - Khrushcheva, Natalya Sergeevna
AU - Lyssenko, Konstantin Alexandrovich
AU - Peregudov, Aleksandr Sergeevich
PY - 2022
DA - 2022/04/29
PB - Mendeleev Communications
SP - 331-333
IS - 3
VL - 32
ER -
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@article{2022_Bulygina,
author = {Ludmila Alekseevna Bulygina and Natalya Sergeevna Khrushcheva and Konstantin Alexandrovich Lyssenko and Aleksandr Sergeevich Peregudov},
title = {Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.012},
number = {3},
pages = {331--333},
doi = {10.1016/j.mencom.2022.05.012}
}
MLA
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Bulygina, Ludmila Alekseevna, et al. “Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction.” Mendeleev Communications, vol. 32, no. 3, Apr. 2022, pp. 331-333. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.012.

Keywords

bicyclic ligand precursor
ferrocene
Palladium complexes
Suzuki reaction
unsymmetrical pincer complexes

Abstract

New bicyclic unsymmetrical CNN palladium 5,6-membered pincer complex was synthesized from 3-ferrocenylmethyl-8-dimethylamino-3-azabicyclo[3.2.1]octane by its direct cyclo-palladation with Li2PdCl4 or Na2PdCl4 and sodium acetate in MeOH. The obtained complex exhibited high catalytic activity in the Suzuki cross-coupling between aryl bromides and phenylboronic acid.

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