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Solvate phases crystallizing from hybrid halide perovskite solutions: Chemical classification and structural relations

, 
Ekaterina Igorevna Marchenko 1, 2
Ekaterina Igorevna Marchenko
,  , 
Yumao Li 1, 3
Yumao Li
, 
Eugene Alekseevich Goodilin 1, 4
Eugene Alekseevich Goodilin
, 
Alexey Borisovich Tarasov 1
Alexey Borisovich Tarasov
10.1016/j.mencom.2022.05.006
Published 2022-04-29
Communication , Volume 32, Issue 3, 311-314
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Petrov A. A. et al. Solvate phases crystallizing from hybrid halide perovskite solutions: Chemical classification and structural relations // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 311-314.
GOST all authors (up to 50) Copy
Petrov A. A., Marchenko E. I., Fateev S. A., Li Y., Goodilin E. A., Tarasov A. B. Solvate phases crystallizing from hybrid halide perovskite solutions: Chemical classification and structural relations // Mendeleev Communications. 2022. Vol. 32. No. 3. pp. 311-314.
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TY - JOUR
DO - 10.1016/j.mencom.2022.05.006
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.006
TI - Solvate phases crystallizing from hybrid halide perovskite solutions: Chemical classification and structural relations
T2 - Mendeleev Communications
AU - Petrov, Andrey Andreevich
AU - Marchenko, Ekaterina Igorevna
AU - Fateev, Sergey Anatol'evich
AU - Li, Yumao
AU - Goodilin, Eugene Alekseevich
AU - Tarasov, Alexey Borisovich
PY - 2022
DA - 2022/04/29
PB - Mendeleev Communications
SP - 311-314
IS - 3
VL - 32
ER -
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@article{2022_Petrov,
author = {Andrey Andreevich Petrov and Ekaterina Igorevna Marchenko and Sergey Anatol'evich Fateev and Yumao Li and Eugene Alekseevich Goodilin and Alexey Borisovich Tarasov},
title = {Solvate phases crystallizing from hybrid halide perovskite solutions: Chemical classification and structural relations},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.006},
number = {3},
pages = {311--314},
doi = {10.1016/j.mencom.2022.05.006}
}
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Petrov, Andrey Andreevich, et al. “Solvate phases crystallizing from hybrid halide perovskite solutions: Chemical classification and structural relations.” Mendeleev Communications, vol. 32, no. 3, Apr. 2022, pp. 311-314. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.05.006.

Keywords

adducts
DMF
DMSO
GBL
hybrid halide perovskites
hybrid perovskites
intermediate phases
solvates

Abstract

Solution crystallization techniques of hybrid lead halides for perovskite photovoltaics, while remaining the most common method for fabricating solar cells, are inevitably complicated by the formation of numerous intermediate solvates that predetermine the morphology and properties of the final perovskite light-harvesting layer. Here, for the first time, a chemical classification of known solvates is proposed based on a comprehensive analysis of their structural features and relationships with possible structural types.

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