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An effective Pd-catalyzed hydroxycarbonylation of olefins with CO and HCOOH

Oleg Leonidovich Eliseev 1
Oleg Leonidovich Eliseev
, 
Tatyana Nikolaevna Bondarenko 1
Tatyana Nikolaevna Bondarenko
, 
Maria Vadimovna Tsapkina 1
Maria Vadimovna Tsapkina
10.1016/j.mencom.2022.03.033
Published 2022-03-06
Communication , Volume 32, Issue 2, 253-255
4
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Eliseev O. L., Bondarenko T. N., Tsapkina M. V. An effective Pd-catalyzed hydroxycarbonylation of olefins with CO and HCOOH // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 253-255.
GOST all authors (up to 50) Copy
Eliseev O. L., Bondarenko T. N., Tsapkina M. V. An effective Pd-catalyzed hydroxycarbonylation of olefins with CO and HCOOH // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 253-255.
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TY - JOUR
DO - 10.1016/j.mencom.2022.03.033
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.033
TI - An effective Pd-catalyzed hydroxycarbonylation of olefins with CO and HCOOH
T2 - Mendeleev Communications
AU - Eliseev, Oleg Leonidovich
AU - Bondarenko, Tatyana Nikolaevna
AU - Tsapkina, Maria Vadimovna
PY - 2022
DA - 2022/03/06
PB - Mendeleev Communications
SP - 253-255
IS - 2
VL - 32
ER -
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@article{2022_Eliseev,
author = {Oleg Leonidovich Eliseev and Tatyana Nikolaevna Bondarenko and Maria Vadimovna Tsapkina},
title = {An effective Pd-catalyzed hydroxycarbonylation of olefins with CO and HCOOH},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.033},
number = {2},
pages = {253--255},
doi = {10.1016/j.mencom.2022.03.033}
}
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Eliseev, Oleg Leonidovich, et al. “An effective Pd-catalyzed hydroxycarbonylation of olefins with CO and HCOOH.” Mendeleev Communications, vol. 32, no. 2, Mar. 2022, pp. 253-255. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.033.

Keywords

carbon monoxide
carboxylic acids
formic acid
hydroxycarbonylation
olefins
palladium

Abstract

A new protocol for Pd-catalyzed regioselective hydroxy-carbonylation of olefins with formic acid under low pressure of carbon monoxide has been developed. The same catalytic system provides good selectivity to 2-phenylpropionic acid in carbonylation of styrene and to linear acids in carbonylation of terminal alkenes. The reaction is highly susceptible to catalyst precursor and solvent nature.

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