Keywords
calixarene
cationic polymerization
polyoxazine
polyoxazoline
ring-opening polymerization
star polymer
sulfonyl chloride
Abstract
New four-arm star poly(2-alkyl-2-oxazolines) and poly(2-alkyl-2-oxazines) were synthesized using sulfochlorinated calix[4]arene derivative as a multifunctional initiator. Their characteristics were investigated by gel permeation chromatography, light scattering and viscometry. The polymer stars obtained were shown to have well-defined architecture and high intramolecular density.
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