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Microporous polymers based on triacetylarenes

Alexey Ivanovich Kovalev 1
Alexey Ivanovich Kovalev
, 
Irina Anatol'evna Khotina 1
Irina Anatol'evna Khotina
10.1016/j.mencom.2022.03.030
Published 2022-03-06
Communication , Volume 32, Issue 2, 244-246
6
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Kovalev A. I., Khotina I. A. Microporous polymers based on triacetylarenes // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 244-246.
GOST all authors (up to 50) Copy
Kovalev A. I., Khotina I. A. Microporous polymers based on triacetylarenes // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 244-246.
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TY - JOUR
DO - 10.1016/j.mencom.2022.03.030
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.030
TI - Microporous polymers based on triacetylarenes
T2 - Mendeleev Communications
AU - Kovalev, Alexey Ivanovich
AU - Khotina, Irina Anatol'evna
PY - 2022
DA - 2022/03/06
PB - Mendeleev Communications
SP - 244-246
IS - 2
VL - 32
ER -
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@article{2022_Kovalev,
author = {Alexey Ivanovich Kovalev and Irina Anatol'evna Khotina},
title = {Microporous polymers based on triacetylarenes},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.030},
number = {2},
pages = {244--246},
doi = {10.1016/j.mencom.2022.03.030}
}
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MLA Copy
Kovalev, Alexey Ivanovich, and Irina Anatol'evna Khotina. “Microporous polymers based on triacetylarenes.” Mendeleev Communications, vol. 32, no. 2, Mar. 2022, pp. 244-246. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.030.

Keywords

diacetylarenes
dimer fragments
infrared spectra
intrinsic surface area
microporous polyphenylenes
phentriyl fragments
polycyclocondensation
triacetylarenes
trimerization

Abstract

Three-dimensional polymers are synthesized by polycondensation of triacetylarenes with the formation of 1,3,5-phentriyl and dimeric diphenylpropenone fragments. Microporous polyphenylenes with an intrinsic surface area of 650–690 m2 g–1 were obtained by additional heating at 450 °C. The values of the intrinsic surface area of polyphenylenes with rigid-chain rod-shaped inter-nodal fragments significantly exceed those of polyphenylenes with a flexible-chain inter-nodal fragments.

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