Home / Publications / Nickel tetrathiooxalate as a cathode material for potassium batteries

Nickel tetrathiooxalate as a cathode material for potassium batteries

Roman Rimovich Kapaev 1
Roman Rimovich Kapaev
, 
Elena Victorovna Shklyaeva 2
Elena Victorovna Shklyaeva
, 
Georgii Georgievich Abashev 2, 3
Georgii Georgievich Abashev
, 
Keith J Stevenson 1
Keith J Stevenson
, 
Pavel Anatol'evich Troshin 4, 5
Pavel Anatol'evich Troshin
10.1016/j.mencom.2022.03.024
Published 2022-03-06
Communication , Volume 32, Issue 2, 226-227
3
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Kapaev R. R. et al. Nickel tetrathiooxalate as a cathode material for potassium batteries // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 226-227.
GOST all authors (up to 50) Copy
Kapaev R. R., Shklyaeva E. V., Abashev G. G., Stevenson K. J., Troshin P. A. Nickel tetrathiooxalate as a cathode material for potassium batteries // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 226-227.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2022.03.024
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.024
TI - Nickel tetrathiooxalate as a cathode material for potassium batteries
T2 - Mendeleev Communications
AU - Kapaev, Roman Rimovich
AU - Shklyaeva, Elena Victorovna
AU - Abashev, Georgii Georgievich
AU - Stevenson, Keith J
AU - Troshin, Pavel Anatol'evich
PY - 2022
DA - 2022/03/06
PB - Mendeleev Communications
SP - 226-227
IS - 2
VL - 32
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2022_Kapaev,
author = {Roman Rimovich Kapaev and Elena Victorovna Shklyaeva and Georgii Georgievich Abashev and Keith J Stevenson and Pavel Anatol'evich Troshin},
title = {Nickel tetrathiooxalate as a cathode material for potassium batteries},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.024},
number = {2},
pages = {226--227},
doi = {10.1016/j.mencom.2022.03.024}
}
MLA
Cite this
MLA Copy
Kapaev, Roman Rimovich, et al. “Nickel tetrathiooxalate as a cathode material for potassium batteries.” Mendeleev Communications, vol. 32, no. 2, Mar. 2022, pp. 226-227. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.024.

Keywords

cathode materials
conductive polymers
coordination polymers
energy storage
K-ion batteries

Abstract

We report a nickel tetrathiooxalate (NiTTO) coordination polymer as a cathode material for potassium batteries. In a potential range of 1.3–3.6 V vs. K+/K, the specific capacity of the material is 209 mA h g−1 at a current density of 0.1 A g−1, which roughly corresponds to the two-electron reduction of polymer repeating units. The charge–discharge mechanisms of NiTTO in potassium cells were examined using operando Raman spectroscopy.

References

1.
Research Development on K-Ion Batteries
Hosaka T., Kubota K., Hameed A.S., Komaba S.
Chemical Reviews, 2020
2.
Advancements and Challenges in Potassium Ion Batteries: A Comprehensive Review
Rajagopalan R., Tang Y., Ji X., Jia C., Wang H.
Advanced Functional Materials, 2020
4.
Morozova P.A., Luchinin N.D., Rupasov D.P., Katorova N.S., Fedotov S.S., Nikitina V.A., Stevenson K.J., Abakumov A.M.
Mendeleev Communications, 2020
5.
Polymer electrolytes for metal-ion batteries
Voropaeva D.Y., Novikova S.A., Yaroslavtsev A.B.
Russian Chemical Reviews, 2020
8.
Towards K-Ion and Na-Ion Batteries as “Beyond Li-Ion”
Kubota K., Dahbi M., Hosaka T., Kumakura S., Komaba S.
Chemical Record, 2018
9.
Solvation and Dynamics of Sodium and Potassium in Ethylene Carbonate from ab Initio Molecular Dynamics Simulations
Pham T.A., Kweon K.E., Samanta A., Lordi V., Pask J.E.
Journal of Physical Chemistry C, 2017
10.
Research Development on Sodium-Ion Batteries
Yabuuchi N., Kubota K., Dahbi M., Komaba S.
Chemical Reviews, 2014
11.
Electrically Conductive Metal–Organic Frameworks
Xie L.S., Skorupskii G., Dincă M.
Chemical Reviews, 2020
12.
Conductive MOFs
Li W., Deng W., Wang G., Xu G.
EnergyChem, 2020
13.
Stabilization of Hexaaminobenzene in a 2D Conductive Metal–Organic Framework for High Power Sodium Storage
Park J., Lee M., Feng D., Huang Z., Hinckley A.C., Yakovenko A., Zou X., Cui Y., Bao Z.
Journal of the American Chemical Society, 2018
14.
Nickel(II) and Copper(II) Coordination Polymers Derived from 1,2,4,5-Tetraaminobenzene for Lithium-Ion Batteries
Kapaev R.R., Olthof S., Zhidkov I.S., Kurmaev E.Z., Stevenson K.J., Meerholz K., Troshin P.A.
Chemistry of Materials, 2019
15.
A nickel coordination polymer derived from 1,2,4,5-tetraaminobenzene for fast and stable potassium battery anodes
Kapaev R.R., Zhidkov I.S., Kurmaev E.Z., Stevenson K.J., Troshin P.A.
Chemical Communications, 2020
16.
Ni‐Based Coordination Polymer as a Promising Anode Material for Potassium Batteries
Kraevaya O.A., Shchurik E.V., Troshin P.A.
Physica Status Solidi (A) Applications and Materials Science, 2020
18.
A highly conductive conjugated coordination polymer for fast-charge sodium-ion batteries: reconsidering its structures
Wu Y., Chen Y., Tang M., Zhu S., Jiang C., Zhuo S., Wang C.
Chemical Communications, 2019
19.
Highly Conductive Two-Dimensional Metal–Organic Frameworks for Resilient Lithium Storage with Superb Rate Capability
Wu Z., Adekoya D., Huang X., Kiefel M.J., Xie J., Xu W., Zhang Q., Zhu D., Zhang S.
ACS Nano, 2020
21.
Robust and conductive two-dimensional metal−organic frameworks with exceptionally high volumetric and areal capacitance
Feng D., Lei T., Lukatskaya M.R., Park J., Huang Z., Lee M., Shaw L., Chen S., Yakovenko A.A., Kulkarni A., Xiao J., Fredrickson K., Tok J.B., Zou X., Cui Y., et. al.
Nature Energy, 2018
22.
Conductive MOF electrodes for stable supercapacitors with high areal capacitance
Sheberla D., Bachman J.C., Elias J.S., Sun C., Shao-Horn Y., Dincă M.
Nature Materials, 2016
24.
10.1016/j.mencom.2022.03.024_b0120
Zhang
ACS Appl. Electron. Mater., 1947
25.
Organic Thermoelectric Materials and Devices Based on p- and n-Type Poly(metal 1,1,2,2-ethenetetrathiolate)s
Sun Y., Sheng P., Di C., Jiao F., Xu W., Qiu D., Zhu D.
Advanced Materials, 2012
26.
Nickel ethylene tetrathiolate polymers as nanoparticles: a new synthesis for future applications?
Faulmann C., Chahine J., Jacob K., Coppel Y., Valade L., de Caro D.
Journal of Nanoparticle Research, 2013
27.
Controlling the Thermoelectric Properties of Organometallic Coordination Polymers via Ligand Design
Liu Z., Liu T., Savory C.N., Jurado J.P., Reparaz J.S., Li J., Pan L., Faul C.F., Parkin I.P., Sankar G., Matsuishi S., Campoy‐Quiles M., Scanlon D.O., Zwijnenburg M.A., Fenwick O., et. al.
Advanced Functional Materials, 2020