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Acidic N-dealkylation in nitrotriazolium salts

Gennady Timofeevich Sukhanov 1
Gennady Timofeevich Sukhanov
, 
Yulia Vadimovna Filippova 1
Yulia Vadimovna Filippova
, 
Yuriy Vasil'evich Gatilov 2
Yuriy Vasil'evich Gatilov
, 
Anna Gennadievna Sukhanova 1
Anna Gennadievna Sukhanova
, 
Konstantin Konstantinovich Bosov 1
Konstantin Konstantinovich Bosov
, 
Irina Aleksandrovna Krupnova 1
Irina Aleksandrovna Krupnova
, 
Ekaterina Valeryevna Pivovarova 1
Ekaterina Valeryevna Pivovarova
1 Institute for Problems of Chemical & Energetic Technologies, Siberian Branch of the Russian Academy of Sciences, Biysk, Russian Federation
10.1016/j.mencom.2022.03.020
Published 2022-03-06
Communication , Volume 32, Issue 2, 215-217
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Sukhanov G. T. et al. Acidic N-dealkylation in nitrotriazolium salts // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 215-217.
GOST all authors (up to 50) Copy
Sukhanov G. T., Filippova Y. V., Gatilov Y. V., Sukhanova A. G., Bosov K. K., Krupnova I. A., Pivovarova E. V. Acidic N-dealkylation in nitrotriazolium salts // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 215-217.
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TY - JOUR
DO - 10.1016/j.mencom.2022.03.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.020
TI - Acidic N-dealkylation in nitrotriazolium salts
T2 - Mendeleev Communications
AU - Sukhanov, Gennady Timofeevich
AU - Filippova, Yulia Vadimovna
AU - Gatilov, Yuriy Vasil'evich
AU - Sukhanova, Anna Gennadievna
AU - Bosov, Konstantin Konstantinovich
AU - Krupnova, Irina Aleksandrovna
AU - Pivovarova, Ekaterina Valeryevna
PY - 2022
DA - 2022/03/06
PB - Mendeleev Communications
SP - 215-217
IS - 2
VL - 32
ER -
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@article{2022_Sukhanov,
author = {Gennady Timofeevich Sukhanov and Yulia Vadimovna Filippova and Yuriy Vasil'evich Gatilov and Anna Gennadievna Sukhanova and Konstantin Konstantinovich Bosov and Irina Aleksandrovna Krupnova and Ekaterina Valeryevna Pivovarova},
title = {Acidic N-dealkylation in nitrotriazolium salts},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.020},
number = {2},
pages = {215--217},
doi = {10.1016/j.mencom.2022.03.020}
}
MLA
Cite this
MLA Copy
Sukhanov, Gennady Timofeevich, et al. “Acidic N-dealkylation in nitrotriazolium salts.” Mendeleev Communications, vol. 32, no. 2, Mar. 2022, pp. 215-217. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.020.

Keywords

1,2,3-triazolium salts
1,2,4-triazolium salts
alkyltriazoles
dealkylation
nitrotriazoles
regioselectivity
SNipso-substitution

Abstract

New selective synthesis of 1-alkyl-5-nitro-1,2,3-triazoles and 1-alkyl-4-nitro-1,2,3-triazoles has been developed, involving acid N-dealkylation of the relative 4-nitro-1,2,3- and 3-nitro- 5-R-1,2,4-triazolium salts. The assortment of novel 1-alkyl- 4(5)-nitro-1,2,3-triazoles has been thus essentially expanded. Treatment of relative 3-nitro-1,2,4-triazolium salts with HCl or HBr proceeds mostly as SNipso-substitution of the nitro group.

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