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Synthesis, crystal structure and thermal properties of Na2Ti(CF3COO)6(CF3COOH)2

, 
Tatyana Yur'evna Glazunova 1
Tatyana Yur'evna Glazunova
, 
Elmira Kharisovna Lermontova 1
Elmira Kharisovna Lermontova
10.1016/j.mencom.2022.03.019
Published 2022-03-06
Communication , Volume 32, Issue 2, 212-214
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Buzoverov M. E., Glazunova T. Y., Lermontova E. K. Synthesis, crystal structure and thermal properties of Na2Ti(CF3COO)6(CF3COOH)2 // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 212-214.
GOST all authors (up to 50) Copy
Buzoverov M. E., Glazunova T. Y., Lermontova E. K. Synthesis, crystal structure and thermal properties of Na2Ti(CF3COO)6(CF3COOH)2 // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 212-214.
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TY - JOUR
DO - 10.1016/j.mencom.2022.03.019
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.019
TI - Synthesis, crystal structure and thermal properties of Na2Ti(CF3COO)6(CF3COOH)2
T2 - Mendeleev Communications
AU - Buzoverov, Mikhail E
AU - Glazunova, Tatyana Yur'evna
AU - Lermontova, Elmira Kharisovna
PY - 2022
DA - 2022/03/06
PB - Mendeleev Communications
SP - 212-214
IS - 2
VL - 32
ER -
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@article{2022_Buzoverov,
author = {Mikhail E Buzoverov and Tatyana Yur'evna Glazunova and Elmira Kharisovna Lermontova},
title = {Synthesis, crystal structure and thermal properties of Na2Ti(CF3COO)6(CF3COOH)2},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.019},
number = {2},
pages = {212--214},
doi = {10.1016/j.mencom.2022.03.019}
}
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Buzoverov, Mikhail E., et al. “Synthesis, crystal structure and thermal properties of Na2Ti(CF3COO)6(CF3COOH)2.” Mendeleev Communications, vol. 32, no. 2, Mar. 2022, pp. 212-214. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.019.

Keywords

carboxylate complexes
titanium
titanium coordination compounds
titanium trifluoroacetate
trifluoroacetic acid

Abstract

The compound Na2Ti(CF3COO)6(CF3COOH)2 was synthesized as colorless crystals, extremely unstable in air, by the reaction of TiCl4 with trifluoroacetic acid and sodium trifluoroacetate. Crystallographic studies have shown that this sodium trifluoroacetatotitanate is the first example of a tetravalent titanium carboxylate [Ti(RCOO)6]2– containing titanium in an octahedral environment of oxygen atoms of carboxylate groups. Thermal decomposition of Na2Ti(CF3COO)6(CF3COOH)2 in an argon atmosphere results in the complex fluoride Na2TiF6.

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