Home / Publications / Synthesis, crystal structure and thermal stability of new copper(II) trichloroacetate complexes

Synthesis, crystal structure and thermal stability of new copper(II) trichloroacetate complexes

, 
Kamilla Ruslanovna Volkova 1
Kamilla Ruslanovna Volkova
, 
Elena Vladimirovna Karpova 1
Elena Vladimirovna Karpova
, 
Victor Aleksandrovich Tafeenko 1
Victor Aleksandrovich Tafeenko
, 
Maxim Aleksandrovich Zakharov 1
Maxim Aleksandrovich Zakharov
10.1016/j.mencom.2022.03.018
Published 2022-03-06
Communication , Volume 32, Issue 2, 208-211
3
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Pushikhina O. S. et al. Synthesis, crystal structure and thermal stability of new copper(II) trichloroacetate complexes // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 208-211.
GOST all authors (up to 50) Copy
Pushikhina O. S., Volkova K. R., Karpova E. V., Tafeenko V. A., Zakharov M. A. Synthesis, crystal structure and thermal stability of new copper(II) trichloroacetate complexes // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 208-211.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2022.03.018
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.018
TI - Synthesis, crystal structure and thermal stability of new copper(II) trichloroacetate complexes
T2 - Mendeleev Communications
AU - Pushikhina, Olga Sergeevna
AU - Volkova, Kamilla Ruslanovna
AU - Karpova, Elena Vladimirovna
AU - Tafeenko, Victor Aleksandrovich
AU - Zakharov, Maxim Aleksandrovich
PY - 2022
DA - 2022/03/06
PB - Mendeleev Communications
SP - 208-211
IS - 2
VL - 32
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2022_Pushikhina,
author = {Olga Sergeevna Pushikhina and Kamilla Ruslanovna Volkova and Elena Vladimirovna Karpova and Victor Aleksandrovich Tafeenko and Maxim Aleksandrovich Zakharov},
title = {Synthesis, crystal structure and thermal stability of new copper(II) trichloroacetate complexes},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.018},
number = {2},
pages = {208--211},
doi = {10.1016/j.mencom.2022.03.018}
}
MLA
Cite this
MLA Copy
Pushikhina, Olga Sergeevna, et al. “Synthesis, crystal structure and thermal stability of new copper(II) trichloroacetate complexes.” Mendeleev Communications, vol. 32, no. 2, Mar. 2022, pp. 208-211. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.018.

Keywords

acetonitrile solvate
basic copper salts
crystal structure
paddle wheel
thermal analysis
trichloroacetate

Abstract

We have synthesized two novel complexes of copper(II) trichloro acetate, Cu2(CCl3COO)3(OH)(H2O)4·H2O and Cu(CCl3COO)2(MeCN), and determined their crystal structures and thermal stability. While the complex with acetonitrile has a discrete binuclear paddle-wheel structure, typical of copper carboxylates, the aqua-hydroxo complex belongs to a novel unique chain–molecular type of basic copper complexes.

References

2.
Lutsenko I.A., Kiskin M.A., Nikolaevskii S.A., Nelyubina Y.V., Primakov P.V., Goloveshkin A.S., Imshennik V.K., Maksimov Y.V., Sidorov A.A., Eremenko I.L.
Mendeleev Communications, 2020
3.
Yambulatov D.S., Nikolaevskii S.A., Shmelev M.A., Babeshkin K.A., Korchagin D.V., Efimov N.N., Goloveshkin A.S., Petrov P.A., Kiskin M.A., Sokolov M.N., Eremenko I.L.
Mendeleev Communications, 2021
8.
Mixed-ligand MnIIand CuIIcomplexes with alternating 2,2′-bipyrimidine and terephthalate bridges
Poleti D., Rogan J., Rodić M.V., Radovanović L.
Acta crystallographica. Section C, Structural chemistry, 2015
10.
Crystal architecture and magnetic properties of four transition-metal adipate coordination polymers
Bakalbassis E.G., Korabik M., Michailides A., Mrozinski J., Raptopoulou C., Skoulika S., Terzis A., Tsaousis D.
Journal of the Chemical Society Dalton Transactions, 2001
13.
SOME SALTS OF THE HALOGENOACETIC ACIDS. II.
Bateman W.G., Conrad D.B.
Journal of the American Chemical Society, 1915
14.
Magnetic and IR studies of copper(II) chloroacetates
Patel K.S., Faniran J.A., Earnshaw A.
Journal of Inorganic and Nuclear Chemistry, 1976
15.
The structures and thermal decomposition of cupric mono, di and trichloracetates
Judd M.D., Plunkett B.A., Pope M.I.
Journal of Thermal Analysis and Calorimetry, 1976
16.
Crystal Structure and35Cl NQR of Copper(II) Trichloroacetate Trihydrate
Kiriyama H., Hashimoto M., Okuno N.
Bulletin of the Chemical Society of Japan, 1987
17.
Structure of copper(II) perchlorate hexahydrate.
Gallucci J.C., Gerkin R.E.
Acta Crystallographica Section C Crystal Structure Communications, 1989
18.
Synthesis and Crystal Structure of Copper(II) Trifluoroacetates, Cu2(CF3COO)4 · 2 CH3CN and Cu(CF3COO)2(H2O)4
Karpova E.V., Boltalin A.I., Zakharov M.A., Sorokina N.I., Korenev Y.M., Troyanov S.I.
Zeitschrift fur Anorganische und Allgemeine Chemie, 1998
19.
Synthesis and Structure of Acetonitrile Solvates of Copper(II) Monofluoroacetate and Silver(I) Trifluoroacetate, [Cu2(CH2FCOO)4· 2CH3CN](CH3CN) and Ag3(CF3COO)3(CH3CN)2
Karpova E.V., Boltalin A.I., Korenev Y.M., Zakharov M.A., Troyanov S.I.
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2001
20.
Synthesis, reactivity and structures of mono- and dihaloacetato complexes of copper(I) and copper(II)
Calderazzo F., Donati N., Englert U., Marchetti F., Pampaloni G., Passarelli V.
Inorganica Chimica Acta, 2003
21.
Synthesis and Crystal Structure of [Cu2(OAc)4(NCMe)2] · 2MeCN
Ghassemzadeh M., Aghapoor K., Neumiiller B.
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1998
23.
A short history of SHELX
Sheldrick G.M.
Acta Crystallographica Section A Foundations of Crystallography, 2007
24.
K. Brandenburg, DIAMOND, Release 2.1d, Crystal Impact GbR, Bonn, Germany, 2000.