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Ruthenium complexes with chelating carboxylate-NHC ligands as efficient catalysts for C–H arylation in water

Konstantin Evgen'evich Shepelenko 1
Konstantin Evgen'evich Shepelenko
, 
Ksenia Alekseevna Nikolaeva 1
Ksenia Alekseevna Nikolaeva
, 
Maxim Aleksandrovich Shevchenko 1
Maxim Aleksandrovich Shevchenko
, 
Yurii Nikolaevich Tkachenko 1
Yurii Nikolaevich Tkachenko
,  , 
Viktor Mikhailovich Chernyshev 1
Viktor Mikhailovich Chernyshev
10.1016/j.mencom.2022.03.017
Published 2022-03-06
Communication , Volume 32, Issue 2, 205-207
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Shepelenko K. E. et al. Ruthenium complexes with chelating carboxylate-NHC ligands as efficient catalysts for C–H arylation in water // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 205-207.
GOST all authors (up to 50) Copy
Shepelenko K. E., Nikolaeva K. A., Shevchenko M. A., Tkachenko Y. N., Minyaev M. E., Chernyshev V. M. Ruthenium complexes with chelating carboxylate-NHC ligands as efficient catalysts for C–H arylation in water // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 205-207.
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TY - JOUR
DO - 10.1016/j.mencom.2022.03.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.017
TI - Ruthenium complexes with chelating carboxylate-NHC ligands as efficient catalysts for C–H arylation in water
T2 - Mendeleev Communications
AU - Shepelenko, Konstantin Evgen'evich
AU - Nikolaeva, Ksenia Alekseevna
AU - Shevchenko, Maxim Aleksandrovich
AU - Tkachenko, Yurii Nikolaevich
AU - Minyaev, Mikhail Evgenievich
AU - Chernyshev, Viktor Mikhailovich
PY - 2022
DA - 2022/03/06
PB - Mendeleev Communications
SP - 205-207
IS - 2
VL - 32
ER -
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@article{2022_Shepelenko,
author = {Konstantin Evgen'evich Shepelenko and Ksenia Alekseevna Nikolaeva and Maxim Aleksandrovich Shevchenko and Yurii Nikolaevich Tkachenko and Mikhail Evgenievich Minyaev and Viktor Mikhailovich Chernyshev},
title = {Ruthenium complexes with chelating carboxylate-NHC ligands as efficient catalysts for C–H arylation in water},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.017},
number = {2},
pages = {205--207},
doi = {10.1016/j.mencom.2022.03.017}
}
MLA
Cite this
MLA Copy
Shepelenko, Konstantin Evgen'evich, et al. “Ruthenium complexes with chelating carboxylate-NHC ligands as efficient catalysts for C–H arylation in water.” Mendeleev Communications, vol. 32, no. 2, Mar. 2022, pp. 205-207. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.017.

Keywords

arylation
carboxylate assistance
CH-activation
N-heterocyclic carbene ligands
ruthenium complexes

Abstract

Ruthenium(ii) complexes with chelating N-heterocyclic carbene (NHC) ligands were studied in the arylation of phenyl group in 2-phenylpyridine and 1-phenylpyrazole with aryl chlorides in water. Complexes with NHC-ligands containing a hemilabile coordinating N-carboxylatomethyl group enable fast and selective ortho-CH-diarylation in the absence of carboxylate-assisting additives.

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