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Ligand-to-ligand charge transfer state in lanthanide complexes containing π-bonded antenna ligands

Daniil Arkadievich Bardonov 1, 2
Daniil Arkadievich Bardonov
, 
Lada Nikolaevna Puntus 1, 3
Lada Nikolaevna Puntus
, 
Il'ya Viktorovich Taidakov 4
Il'ya Viktorovich Taidakov
, 
Evgenia Aleksandrovna Varaksina 4
Evgenia Aleksandrovna Varaksina
, 
Konstantin Alexandrovich Lyssenko 5, 6
Konstantin Alexandrovich Lyssenko
, 
Ilya Eduardovich Nifant'ev 1, 2, 5
Ilya Eduardovich Nifant'ev
, 
Dmitrii Mikhailovich Roitershtein 1, 2, 7
Dmitrii Mikhailovich Roitershtein
10.1016/j.mencom.2022.03.015
Published 2022-03-06
Communication , Volume 32, Issue 2, 198-201
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Bardonov D. A. et al. Ligand-to-ligand charge transfer state in lanthanide complexes containing π-bonded antenna ligands // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 198-201.
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Bardonov D. A., Puntus L. N., Taidakov I. V., Varaksina E. A., Lyssenko K. A., Nifant'ev I. E., Roitershtein D. M. Ligand-to-ligand charge transfer state in lanthanide complexes containing π-bonded antenna ligands // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 198-201.
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TY - JOUR
DO - 10.1016/j.mencom.2022.03.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.015
TI - Ligand-to-ligand charge transfer state in lanthanide complexes containing π-bonded antenna ligands
T2 - Mendeleev Communications
AU - Bardonov, Daniil Arkadievich
AU - Puntus, Lada Nikolaevna
AU - Taidakov, Il'ya Viktorovich
AU - Varaksina, Evgenia Aleksandrovna
AU - Lyssenko, Konstantin Alexandrovich
AU - Nifant'ev, Ilya Eduardovich
AU - Roitershtein, Dmitrii Mikhailovich
PY - 2022
DA - 2022/03/06
PB - Mendeleev Communications
SP - 198-201
IS - 2
VL - 32
ER -
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@article{2022_Bardonov,
author = {Daniil Arkadievich Bardonov and Lada Nikolaevna Puntus and Il'ya Viktorovich Taidakov and Evgenia Aleksandrovna Varaksina and Konstantin Alexandrovich Lyssenko and Ilya Eduardovich Nifant'ev and Dmitrii Mikhailovich Roitershtein},
title = {Ligand-to-ligand charge transfer state in lanthanide complexes containing π-bonded antenna ligands},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.015},
number = {2},
pages = {198--201},
doi = {10.1016/j.mencom.2022.03.015}
}
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Bardonov, Daniil Arkadievich, et al. “Ligand-to-ligand charge transfer state in lanthanide complexes containing π-bonded antenna ligands.” Mendeleev Communications, vol. 32, no. 2, Mar. 2022, pp. 198-201. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.015.

Keywords

charge transfer state
Cp ligand
crystal structure
lanthanide complexes
NIR luminescence

Abstract

To design luminescent lanthanide complexes containing both π- and σ-bonded antenna ligands in the coordination sphere, we synthesized 2,2′-bipyridine complexes of Nd, Tb and Gd with tri- and tetraphenyl substituted cyclopentadienyl ligands: [CpPh3LnCl2(bipy)(THF)] (CpPh3 = 1,2,4-triphenylcyclopenta- dienyl, bipy = 2,2′-bipyridine) and [CpPh4LnCl2(bipy)(THF)] (CpPh4 = tetraphenylcyclopentadienyl). Their crystal structures were determined by X-ray diffraction analysis. Optical spectroscopic and crystallographic data indicate the presence of a ligand-to-ligand charge transfer state.

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