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Transition metal atoms grafted on the nanodiamonds surface: Identification and guest–host spin–spin interactions

Ilya Dmitrievich Gridnev 1
Ilya Dmitrievich Gridnev
, 
Vladimir Yur'evich Osipov 2
Vladimir Yur'evich Osipov
10.1016/j.mencom.2022.03.001
Published 2022-03-06
Focus article , Volume 32, Issue 2, 143-151
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Gridnev I. D., Osipov V. Y. Transition metal atoms grafted on the nanodiamonds surface: Identification and guest–host spin–spin interactions // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 143-151.
GOST all authors (up to 50) Copy
Gridnev I. D., Osipov V. Y. Transition metal atoms grafted on the nanodiamonds surface: Identification and guest–host spin–spin interactions // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 143-151.
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TY - JOUR
DO - 10.1016/j.mencom.2022.03.001
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.001
TI - Transition metal atoms grafted on the nanodiamonds surface: Identification and guest–host spin–spin interactions
T2 - Mendeleev Communications
AU - Gridnev, Ilya Dmitrievich
AU - Osipov, Vladimir Yur'evich
PY - 2022
DA - 2022/03/06
PB - Mendeleev Communications
SP - 143-151
IS - 2
VL - 32
ER -
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@article{2022_Gridnev,
author = {Ilya Dmitrievich Gridnev and Vladimir Yur'evich Osipov},
title = {Transition metal atoms grafted on the nanodiamonds surface: Identification and guest–host spin–spin interactions},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.001},
number = {2},
pages = {143--151},
doi = {10.1016/j.mencom.2022.03.001}
}
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Gridnev, Ilya Dmitrievich, and Vladimir Yur'evich Osipov. “Transition metal atoms grafted on the nanodiamonds surface: Identification and guest–host spin–spin interactions.” Mendeleev Communications, vol. 32, no. 2, Mar. 2022, pp. 143-151. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.03.001.
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Keywords

3d/4f-metals
chelate complexes
density functional theory
electron paramagnetic resonance
magnetochemistry
nanodiamonds

Abstract

This survey describes recent achievements in creating a new type of materials – nanodiamonds grafted with atoms of transition metals. Structural features of some selected chelate complexes studied by density functional theory, their scope and limitations as well as possible applications are discussed. Using the example of copper ions, their location relative to subsurface defects of detonation diamond is investigated by the method of electron paramagnetic resonance (EPR).

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