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Composition of petroleum asphaltenes derived from ruthenium-catalyzed oxidation

Tatiana Viktorovna Cheshkova 1
Tatiana Viktorovna Cheshkova
, 
Elena Yur'evna Kovalenko 1
Elena Yur'evna Kovalenko
, 
Tatiana Anatol'evna Sagachenko 1
Tatiana Anatol'evna Sagachenko
, 
Raisa Sergeevna Min 1
Raisa Sergeevna Min
, 
Eugenia Borisovna Golushkova 2
Eugenia Borisovna Golushkova
10.1016/j.mencom.2022.01.045
Published 2022-01-03
Communication , Volume 32, Issue 1, 139-141
3
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Cheshkova T. V. et al. Composition of petroleum asphaltenes derived from ruthenium-catalyzed oxidation // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 139-141.
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Cheshkova T. V., Kovalenko E. Y., Sagachenko T. A., Min R. S., Golushkova E. B. Composition of petroleum asphaltenes derived from ruthenium-catalyzed oxidation // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 139-141.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.045
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.045
TI - Composition of petroleum asphaltenes derived from ruthenium-catalyzed oxidation
T2 - Mendeleev Communications
AU - Cheshkova, Tatiana Viktorovna
AU - Kovalenko, Elena Yur'evna
AU - Sagachenko, Tatiana Anatol'evna
AU - Min, Raisa Sergeevna
AU - Golushkova, Eugenia Borisovna
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 139-141
IS - 1
VL - 32
ER -
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@article{2022_Cheshkova,
author = {Tatiana Viktorovna Cheshkova and Elena Yur'evna Kovalenko and Tatiana Anatol'evna Sagachenko and Raisa Sergeevna Min and Eugenia Borisovna Golushkova},
title = {Composition of petroleum asphaltenes derived from ruthenium-catalyzed oxidation},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.045},
number = {1},
pages = {139--141},
doi = {10.1016/j.mencom.2022.01.045}
}
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Cheshkova, Tatiana Viktorovna, et al. “Composition of petroleum asphaltenes derived from ruthenium-catalyzed oxidation.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 139-141. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.045.

Keywords

alkylarenes
arylalkanes
asphaltenes
catalysis
esters
mass spectrometry
oxidation
phthalic anhydride
ruthenium ions

Abstract

Ruthenium ion-catalyzed oxidation of methanonaphthene oil (Krapivinskoye oilfield) revealed that its high molecular asphaltenes contain aromatic–aliphatic bridges and non- covalently bound (occluded) compounds. Covalently bound fragments are represented by C5–C18 n-alkanes, aromatic biphenyl-type structures, and naphthalenes located in the peripheral part of asphaltene molecules. Typical biological markers, i.e. terpanes, steranes, and n-alkanes have been identified among the occluded compounds.

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