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Magnetic resonance tracking of copper ion fixation on the surface of carboxylated nanodiamonds from viewpoint of changes in carbon-inherited paramagnetism

Vladimir Yur'evich Osipov 1
Vladimir Yur'evich Osipov
, 
Nikolai Mikhailovich Romanov 2, 3
Nikolai Mikhailovich Romanov
, 
Inna Èduardovna Suvorkova 4
Inna Èduardovna Suvorkova
, 
Ekaterina Victorovna Osipova 5
Ekaterina Victorovna Osipova
, 
Takuma Tsuji 6
Takuma Tsuji
, 
Yasushi Ishiguro 7
Yasushi Ishiguro
, 
Kazuyuki Takai 6
Kazuyuki Takai
10.1016/j.mencom.2022.01.043
Published 2022-01-03
Communication , Volume 32, Issue 1, 132-135
6
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Osipov V. Y. et al. Magnetic resonance tracking of copper ion fixation on the surface of carboxylated nanodiamonds from viewpoint of changes in carbon-inherited paramagnetism // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 132-135.
GOST all authors (up to 50) Copy
Osipov V. Y., Romanov N. M., Suvorkova I. È., Osipova E. V., Tsuji T., Ishiguro Y., Takai K. Magnetic resonance tracking of copper ion fixation on the surface of carboxylated nanodiamonds from viewpoint of changes in carbon-inherited paramagnetism // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 132-135.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.043
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.043
TI - Magnetic resonance tracking of copper ion fixation on the surface of carboxylated nanodiamonds from viewpoint of changes in carbon-inherited paramagnetism
T2 - Mendeleev Communications
AU - Osipov, Vladimir Yur'evich
AU - Romanov, Nikolai Mikhailovich
AU - Suvorkova, Inna Èduardovna
AU - Osipova, Ekaterina Victorovna
AU - Tsuji, Takuma
AU - Ishiguro, Yasushi
AU - Takai, Kazuyuki
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 132-135
IS - 1
VL - 32
ER -
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@article{2022_Osipov,
author = {Vladimir Yur'evich Osipov and Nikolai Mikhailovich Romanov and Inna Èduardovna Suvorkova and Ekaterina Victorovna Osipova and Takuma Tsuji and Yasushi Ishiguro and Kazuyuki Takai},
title = {Magnetic resonance tracking of copper ion fixation on the surface of carboxylated nanodiamonds from viewpoint of changes in carbon-inherited paramagnetism},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.043},
number = {1},
pages = {132--135},
doi = {10.1016/j.mencom.2022.01.043}
}
MLA
Cite this
MLA Copy
Osipov, Vladimir Yur'evich, et al. “Magnetic resonance tracking of copper ion fixation on the surface of carboxylated nanodiamonds from viewpoint of changes in carbon-inherited paramagnetism.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 132-135. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.043.

Keywords

chelate complexes
copper ions
detonation nanodiamond
electron paramagnetic resonance
elemental analysis
spin paramagnetism
surface functional groups

Abstract

Detonation nanodiamonds with a particle size of 5 nm and a carboxylated surface are easily modified by doubly charged copper ions to form copper chelate complexes. The concentration of copper complexes in a dry powder of such nanodiamonds is well monitored by the method of electron paramagnetic resonance, both by the signal width of intrinsic paramagnetic centers in nanodiamonds and by the signal shape for the surface Cu2+ ions themselves, including the set of hyperfine splitting lines for the parallel component and the line with an unresolved hyperfine structure for the perpendicular component.

References

1.
Detonation Nanodiamonds: Science and Applications, eds. A. Ya. Vul’ and O. A. Shenderova, Pan Stanford, Singapore, 2014.
2.
Nanodiamonds: Advanced Material Analysis, Properties and Applications, ed. J.-C. Arnault, Elsevier, Amsterdam, 2017.
3.
CHAPTER 3. The Chemistry of Nanodiamond
Krueger A.
RSC Nanoscience and Nanotechnology, 2014
4.
Detonation nanodiamonds: new aspects in the theory and practice of synthesis, properties and applications
Dolmatov V.Y., Ozerin A.N., Kulakova I.I., Bochechka O.O., Lapchuk N.M., Myllymäki V., Vehanen A.
Russian Chemical Reviews, 2020
5.
Solid State NMR study of nanodiamond surface chemistry
Dubois M., Guérin K., Batisse N., Petit E., Hamwi A., Komatsu N., Kharbache H., Pirotte P., Masin F.
Solid State Nuclear Magnetic Resonance, 2011
6.
Solid-State NMR Study of Nanodiamonds Produced by the Detonation Technique
Dubois M., Guérin K., Petit E., Batisse N., Hamwi A., Komatsu N., Giraudet J., Pirotte P., Masin F.
Journal of Physical Chemistry C, 2009
7.
NMR and EPR Characterization of Functionalized Nanodiamonds
Presti C., Thankamony A.S., Alauzun J.G., Mutin P.H., Carnevale D., Lion C., Vezin H., Laurencin D., Lafon O.
Journal of Physical Chemistry C, 2015
8.
Osipov V.Y., Romanov N.M., Kogane K., Touhara H., Hattori Y., Takai K.
Mendeleev Communications, 2020
9.
Infrared absorption study of surface functional groups providing chemical modification of nanodiamonds by divalent copper ion complexes
Osipov V.Y., Aleksenskiy A.E., Shames A.I., Panich A.M., Shestakov M.S., Vul’ A.Y.
Diamond and Related Materials, 2011
10.
10.1016/j.mencom.2022.01.043_b0050
Lim
Int. J. Nanomed., 2016
12.
Magnetic Resonance Study of Gadolinium-Grafted Nanodiamonds
Panich A.M., Shames A.I., Sergeev N.A., Osipov V.Y., Alexenskiy A.E., Vul’ A.Y.
Journal of Physical Chemistry C, 2016
13.
Gadolinium-Complexed Carboxylated Nanodiamond Particles for Magnetic Resonance Imaging of the Lymphatic System
Yano K., Matsumoto T., Okamoto Y., Bito K., Kurokawa N., Hasebe T., Hotta A.
ACS Applied Nano Materials, 2021
14.
Combined Experimental and DFT Study of the Chemical Binding of Copper Ions on the Surface of Nanodiamonds
Gridnev I.D., Osipov V.Y., Aleksenskii A.E., Vul’ A.Y., Enoki T.
Bulletin of the Chemical Society of Japan, 2014
15.
Structure and magnetic properties of detonation nanodiamond chemically modified by copper
Shames A.I., Panich A.M., Osipov V.Y., Aleksenskiy A.E., Vul’ A.Y., Enoki T., Takai K.
Journal of Applied Physics, 2010
17.
Locating inherent unpaired orbital spins in detonation nanodiamonds through the targeted surface decoration by paramagnetic probes
Shames A.I., Osipov V.Y., Aleksenskiy A.E., Ōsawa E., Vul' A.Y.
Diamond and Related Materials, 2011
18.
10.1016/j.mencom.2022.01.043_b0090
Wertz
Electron Spin Resonance: Elementary Theory and Practical Applications, 1972
19.
10.1016/j.mencom.2022.01.043_b0095
Lund
Principles and Applications of ESR Spectroscopy, 2011
20.
Nonaromatic Core−Shell Structure of Nanodiamond from Solid-State NMR Spectroscopy
Fang X., Mao J., Levin E.M., Schmidt-Rohr K.
Journal of the American Chemical Society, 2009
21.
Aberration-corrected microscopy and spectroscopy analysis of pristine, nitrogen containing detonation nanodiamond
Turner S., Shenderova O., Da Pieve F., Lu Y., Yücelen E., Verbeeck J., Lamoen D., Van Tendeloo G.
Physica Status Solidi (A) Applications and Materials Science, 2013
22.
10.1016/j.mencom.2022.01.043_b0110
Dobrinets
HPHT-Treated Diamonds: Diamonds Forever, 2013
23.
10.1016/j.mencom.2022.01.043_b0115
Kobayashi
J. Chem. Phys., 1983
24.
10.1016/j.mencom.2022.01.043_b0120
Slichter
Principles of Magnetic Resonance, 1963
25.
J. F. Moulder, W. F. Stickle, P. E. Sobol and K. D. Bomben, Handbook of X-ray Photoelectron Spectroscopy, ed. J. Chastain, Perkin-Elmer Corp., Eden Prairie, MN, 1992.
26.
10.1016/j.mencom.2022.01.043_b0130
van der Heide
X-ray Photoelectron Spectroscopy: An Introduction to Principles and Practices, 2011
27.
Optical properties of nanodiamond layers
Aleksenskii A.E., Osipov V.Y., Vul’ A.Y., Ber B.Y., Smirnov A.B., Melekhin V.G., Adriaenssens G.J., Iakoubovskii K.
Physics of the Solid State, 2001
29.
Water-selective adsorption sites on detonation nanodiamonds
Piña-Salazar E., Kukobat R., Futamura R., Hayashi T., Toshio S., Ōsawa E., Kaneko K.
Carbon, 2018
30.
X-ray photoelectron spectroscopy of copper compounds
Frost D.C., Ishitani A., McDowell C.A.
Molecular Physics, 1972