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Stoichiometry-dependent oxidation of tris(2-methoxyphenyl)antimony with diiodine

Vladimir Viktorovich Sharutin 1
Vladimir Viktorovich Sharutin
,  , 
Andrey N Efremov 1
Andrey N Efremov
, 
Sergey Alexandrovich Adonin 1, 2
Sergey Alexandrovich Adonin
10.1016/j.mencom.2022.01.035
Published 2022-01-03
Communication , Volume 32, Issue 1, 109-110
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Sharutin V. V. et al. Stoichiometry-dependent oxidation of tris(2-methoxyphenyl)antimony with diiodine // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 109-110.
GOST all authors (up to 50) Copy
Sharutin V. V., Sharutina O. K., Efremov A. N., Adonin S. A. Stoichiometry-dependent oxidation of tris(2-methoxyphenyl)antimony with diiodine // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 109-110.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.035
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.035
TI - Stoichiometry-dependent oxidation of tris(2-methoxyphenyl)antimony with diiodine
T2 - Mendeleev Communications
AU - Sharutin, Vladimir Viktorovich
AU - Sharutina, Olga Konstantinovna
AU - Efremov, Andrey N
AU - Adonin, Sergey Alexandrovich
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 109-110
IS - 1
VL - 32
ER -
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@article{2022_Sharutin,
author = {Vladimir Viktorovich Sharutin and Olga Konstantinovna Sharutina and Andrey N Efremov and Sergey Alexandrovich Adonin},
title = {Stoichiometry-dependent oxidation of tris(2-methoxyphenyl)antimony with diiodine},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.035},
number = {1},
pages = {109--110},
doi = {10.1016/j.mencom.2022.01.035}
}
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Sharutin, Vladimir Viktorovich, et al. “Stoichiometry-dependent oxidation of tris(2-methoxyphenyl)antimony with diiodine.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 109-110. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.035.

Keywords

antimony
crystal structure
iodine
non-covalent interactions
organoantimony compounds
organometallic compounds

Abstract

The reaction of 2-methoxyphenyllithium with SbCl3 affords tris(2-methoxyphenyl)antimony. Its treatment with equimolar amount of I2 results in stiborane (2-MeOC6H4)3SbI2, while heating with 2 equivalents of I2 leads to iodotris(2-methoxyphenyl)stibonium triiodide [(2-MeOC6H4)3SbI]+ [I3]– featuring halogen bonding in solid state.

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