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Calcium-based coordination polymers from a solvothermal synthesis of HKUST-1 in 3D printed autoclaves

Petr Vital'evich Primakov 1, 2
Petr Vital'evich Primakov
, 
Gleb Leonidovich Denisov 1
Gleb Leonidovich Denisov
, 
Valentin Vladimirovich Novikov 1
Valentin Vladimirovich Novikov
, 
Olga Leont'evna Lependina 1
Olga Leont'evna Lependina
, 
Alexander Aleksandrovich Korlyukov 1
Alexander Aleksandrovich Korlyukov
, 
10.1016/j.mencom.2022.01.034
Published 2022-01-03
Communication , Volume 32, Issue 1, 105-108
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Primakov P. V. et al. Calcium-based coordination polymers from a solvothermal synthesis of HKUST-1 in 3D printed autoclaves // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 105-108.
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Primakov P. V., Denisov G. L., Novikov V. V., Lependina O. L., Korlyukov A. A., Nelyubina Y. V. Calcium-based coordination polymers from a solvothermal synthesis of HKUST-1 in 3D printed autoclaves // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 105-108.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.034
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.034
TI - Calcium-based coordination polymers from a solvothermal synthesis of HKUST-1 in 3D printed autoclaves
T2 - Mendeleev Communications
AU - Primakov, Petr Vital'evich
AU - Denisov, Gleb Leonidovich
AU - Novikov, Valentin Vladimirovich
AU - Lependina, Olga Leont'evna
AU - Korlyukov, Alexander Aleksandrovich
AU - Nelyubina, Yulia Vladimirovna
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 105-108
IS - 1
VL - 32
ER -
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@article{2022_Primakov,
author = {Petr Vital'evich Primakov and Gleb Leonidovich Denisov and Valentin Vladimirovich Novikov and Olga Leont'evna Lependina and Alexander Aleksandrovich Korlyukov and Yulia Vladimirovna Nelyubina},
title = {Calcium-based coordination polymers from a solvothermal synthesis of HKUST-1 in 3D printed autoclaves},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.034},
number = {1},
pages = {105--108},
doi = {10.1016/j.mencom.2022.01.034}
}
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MLA Copy
Primakov, Petr Vital'evich, et al. “Calcium-based coordination polymers from a solvothermal synthesis of HKUST-1 in 3D printed autoclaves.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 105-108. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.034.

Keywords

3D printed reactionware
3D printing
autoclave
crystal structure
metal–organic coordination polymer
polypropylene
solvothermal synthesis
X-ray diffraction

Abstract

A mixed-metal 1D coordination polymer [CaCu(HBTC)2(H2O)8]n (where H3BTC – benzene-1,3,5-tric arboxylic acid) was obtained in a solvothermal synthesis of a well-known copper-containing metal–organic framework [Cu3(BTC)2(H2O)3]n (HKUST-1) in autoclaves 3D-printed from commercial polypropylene. This material was a source of calcium ions, apparently, leaking from a colorant (calcium carbonate) promoted by glacial acetic acid as a modulator used to produce large single crystals of HKUST-1. This finding was confirmed by elemental analysis and a model experiment that resulted in a new calcium-based 1D coordination polymer [Ca(H2BTC)2(H2O)5]n under the same solvothermal conditions with no copper or calcium salts put into a 3D-printed autoclave.

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