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Oxy- and aminoselenation of alkenes utilizing an isolable selenenyl iodide

Satoru Kuwano 1
Satoru Kuwano
, 
Erika Takahashi 1
Erika Takahashi
, 
Kazuaki Ebisawa 1
Kazuaki Ebisawa
, 
Yo Ishikawa 1
Yo Ishikawa
, 
Shohei Sase 1
Shohei Sase
, 
Kei Goto 1
Kei Goto
10.1016/j.mencom.2022.01.026
Published 2022-01-03
Communication , Volume 32, Issue 1, 80-82
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Kuwano S. et al. Oxy- and aminoselenation of alkenes utilizing an isolable selenenyl iodide // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 80-82.
GOST all authors (up to 50) Copy
Kuwano S., Takahashi E., Ebisawa K., Ishikawa Y., Sase S., Goto K. Oxy- and aminoselenation of alkenes utilizing an isolable selenenyl iodide // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 80-82.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.026
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.026
TI - Oxy- and aminoselenation of alkenes utilizing an isolable selenenyl iodide
T2 - Mendeleev Communications
AU - Kuwano, Satoru
AU - Takahashi, Erika
AU - Ebisawa, Kazuaki
AU - Ishikawa, Yo
AU - Sase, Shohei
AU - Goto, Kei
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 80-82
IS - 1
VL - 32
ER -
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@article{2022_Kuwano,
author = {Satoru Kuwano and Erika Takahashi and Kazuaki Ebisawa and Yo Ishikawa and Shohei Sase and Kei Goto},
title = {Oxy- and aminoselenation of alkenes utilizing an isolable selenenyl iodide},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.026},
number = {1},
pages = {80--82},
doi = {10.1016/j.mencom.2022.01.026}
}
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Cite this
MLA Copy
Kuwano, Satoru, et al. “Oxy- and aminoselenation of alkenes utilizing an isolable selenenyl iodide.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 80-82. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.026.

Keywords

alkenes
amines
esters
ethers
organoselenium compounds
selenation
selenenyl iodides

Abstract

Application of an isolable selenenyl iodide BpqSeI (Bpq denotes 5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetra-isopropyl-1,1':3',1'':3'',1''':3''',1''''-quinquephenyl-2''-yl) to selenofunctionalization of alkenes with external oxygen or nitrogen nucleophiles was investigated. In the presence of N-iodosuccinimide as an additive, alcohols, a carboxylic acid, or aromatic amines were smoothly introduced to alkenes to give the corresponding β-oxy or β-amino selenides in moderate to high yields.

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