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Silver-mediated intramolecular P–C coupling

György Szalóki 1
György Szalóki
, 
Karinne Miqueu 2
Karinne Miqueu
, 
Didier Bourissou 1
Didier Bourissou
2 CNRS/Université de Pau et des Pays de l’Adour, Institut des Sciences Analytiques et de Physico-Chimie pour l’Environnement et les Matériaux, Pau Cedex, France
10.1016/j.mencom.2022.01.025
Published 2022-01-03
Communication , Volume 32, Issue 1, 78-79
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Szalóki G., Miqueu K., Bourissou D. Silver-mediated intramolecular P–C coupling // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 78-79.
GOST all authors (up to 50) Copy
Szalóki G., Miqueu K., Bourissou D. Silver-mediated intramolecular P–C coupling // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 78-79.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.025
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.025
TI - Silver-mediated intramolecular P–C coupling
T2 - Mendeleev Communications
AU - Szalóki, György
AU - Miqueu, Karinne
AU - Bourissou, Didier
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 78-79
IS - 1
VL - 32
ER -
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@article{2022_Szalóki,
author = {György Szalóki and Karinne Miqueu and Didier Bourissou},
title = {Silver-mediated intramolecular P–C coupling},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.025},
number = {1},
pages = {78--79},
doi = {10.1016/j.mencom.2022.01.025}
}
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MLA Copy
Szalóki, György, et al. “Silver-mediated intramolecular P–C coupling.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 78-79. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.025.

Keywords

peri substitution
complexes
cross-coupling
DFT
naphthalene
oxidative addition
phosphonium salts
silver

Abstract

Silver(I) salts mimic copper(I) but not gold(I) salts in the reaction with peri-iodo naphthyldiisopropylphosphine. The formation of the corresponding peri-cyclic phosphonium derivatives represents the first example of silver-mediated P–C coupling through a two-electron redox sequence.

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